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The nature of the second dimension in 2D NMR

 

作者: Daniel D. Traficante,  

 

期刊: Concepts in Magnetic Resonance  (WILEY Available online 1989)
卷期: Volume 1, issue 1  

页码: 7-13

 

ISSN:1043-7347

 

年代: 1989

 

DOI:10.1002/cmr.1820010105

 

出版商: John Wiley&Sons, Inc.

 

数据来源: WILEY

 

摘要:

AbstractA two‐dimensional (2D) NMR spectrum is produced from the double Fourier Transform (FT) of two time domains,t1andt2. One of these domains,t2, is identical to the acquisition time used to collect a Free Induction Decay (FID) in one‐dimensional (1D) NMR spectroscopy. After performing the FTs of a series of these FIDs, an array of resonance lines is obtained whose amplitudes and phases are a function oft1. Thet1domain is then composed of another series of “FIDs” that are related to those collected duringt2. In this article, it is shown that in a heteronuclear‐J, δ gated‐decoupling experiment, the “FIDs” in thet1domain produce, after the FT, proton‐coupled spectra whose sum is identical to that obtained from a 1D carbon FID collected with no

 

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