The nature of the second dimension in 2D NMR
作者:
Daniel D. Traficante,
期刊:
Concepts in Magnetic Resonance
(WILEY Available online 1989)
卷期:
Volume 1,
issue 1
页码: 7-13
ISSN:1043-7347
年代: 1989
DOI:10.1002/cmr.1820010105
出版商: John Wiley&Sons, Inc.
数据来源: WILEY
摘要:
AbstractA two‐dimensional (2D) NMR spectrum is produced from the double Fourier Transform (FT) of two time domains,t1andt2. One of these domains,t2, is identical to the acquisition time used to collect a Free Induction Decay (FID) in one‐dimensional (1D) NMR spectroscopy. After performing the FTs of a series of these FIDs, an array of resonance lines is obtained whose amplitudes and phases are a function oft1. Thet1domain is then composed of another series of “FIDs” that are related to those collected duringt2. In this article, it is shown that in a heteronuclear‐J, δ gated‐decoupling experiment, the “FIDs” in thet1domain produce, after the FT, proton‐coupled spectra whose sum is identical to that obtained from a 1D carbon FID collected with no
点击下载:
PDF
(351KB)
返 回