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Temperature dependence of the Raman spectra of NaClO4in relation to the 581 K phase transition

 

作者: N. Toupry‐Krauzman,   H. Poulet,  

 

期刊: Journal of Raman Spectroscopy  （WILEY Available online 1978）
卷期: Volume 7, issue 1  

页码: 1-6

 

ISSN:0377-0486

 

年代: 1978

 

DOI:10.1002/jrs.1250070105

 

出版商: John Wiley&Sons, Ltd.

 

数据来源: WILEY

 

摘要:

AbstractThe evolution of the internal and external modes in the Raman spectra of NaClO4has been studied in the neighbourhood of the transition temperature, at 581 K. Large changes in the frequencies of the external modes with temperature have been observed. These changes can be explained in terms of a model based on the reorientation of the perchlorate ions.

 

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