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Thermoacoustic enhancement of photoacoustic spectroscopy: Theory and measurements of the signal to noise ratioa)

 

作者: W. Patrick Arnott,   Hans Moosmu¨ller,   Robert E. Abbott,   Michael D. Ossofsky,  

 

期刊: Review of Scientific Instruments  (AIP Available online 1995)
卷期: Volume 66, issue 10  

页码: 4827-4833

 

ISSN:0034-6748

 

年代: 1995

 

DOI:10.1063/1.1146159

 

出版商: AIP

 

数据来源: AIP

 

摘要:

Recent developments in thermoacoustics have shown that the quality factor,Q, of an acoustic resonator can be controlled by establishing a temperature gradient across properly positioned thermoacoustic elements. Quite separate from thermoacoustics, acoustic resonators are used in photoacoustic spectroscopy, where a laser beam, modulated at the acoustic resonance frequency, is partially absorbed, thereby producing sound. The photoacoustic signal is typically measured with a microphone, and is proportional to the laser power, to the absorption coefficient, and to the resonatorQ, among other factors. The acoustic signal to noise ratio is proportional toQ1/2. Thermoacoustics can be used to enhance the signal to noise ratio of photoacoustic spectrometers by increasingQ. Measurements and theory are reported for the signal to noise ratio of a photoacoustic cell, with thermoacoustic enhancement, as a function of both resonatorQand the bandwidth of the lock‐in amplifier. Regimes where thermoacoustic enhancement is useful are identified. ©1995 American Institute of Physics.

 

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