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Temperature and bias-field dependences of dielectric behaviour in the antiferroelectric liquid crystal, (R)-MHPOBC

 

作者: J. HOU,   J. SCHACHT,   F. GIEssELMANN,   P. ZUGENMAIER,  

 

期刊: Liquid Crystals  (Taylor Available online 1997)
卷期: Volume 22, issue 4  

页码: 409-417

 

ISSN:0267-8292

 

年代: 1997

 

DOI:10.1080/026782997209126

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Temperature and bias-field dependences of dielectric behaviour in the antiferroelectric liquid crystal, R-MHPOBC, were investigated (see also previous paper). There are mainly two relaxation modes in the SmC*alpha and SmC* phases: one behaves as the soft-mode, which shows significant slowing down in the SmA* and SmC*alpha phases; the other one appears at lower frequencies and changes the dielectric strength remarkably, especially in the SmC* phase, which is considered to relate to the azimuthal phase-fluctuation of molecules in the parallel tilt sequences of the smectic layers. These two modes show different bias field dependences in different C* subphases. In the SmC*A phase, two other types of relaxation mode were observed, which are probably due to the in-phase and anti-phase azimuthal angle fluctuations of molecules in the anti-tilt pairs.

 

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