Determination of multicomponent sorption equilibria using perturbation gas chromatography
作者:
C. J. Glover,
W. R. Lau,
期刊:
AIChE Journal
(WILEY Available online 1983)
卷期:
Volume 29,
issue 1
页码: 73-79
ISSN:0001-1541
年代: 1983
DOI:10.1002/aic.690290110
出版商: American Institute of Chemical Engineers
数据来源: WILEY
摘要:
AbstractPerturbation chromatography previously has been used experimentally as an efficient method for obtaining sorption equilibria for systems with up to two vapor phase components at finite concentration. The objective of this work was to obtain a theoretical result that could be used for experimental determinations of sorption of multiple interfering species at finite concentration. Results obtained are applicable for both non‐stoichiometric and stoichiometric situations for systems that may have flowing phase velocity and volume changes associated with interphase transport and also may have interactions among the sorbed components. The dependence of each effluent peak characteristic velocity upon all of the component equilibrium isotherms requires that the equilibria be considered as a whole by simultaneously fitting a set of composition grid perturbation response data to appropriate isotherm surface equation
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