Intervalence Transfer Spectra of Vanadium(III) Prussian Blue Complexes
作者:
HenriqueE. Toma,
FernandoT. P. Lellis,
期刊:
Spectroscopy Letters
(Taylor Available online 1988)
卷期:
Volume 21,
issue 1
页码: 45-54
ISSN:0038-7010
年代: 1988
DOI:10.1080/00387018808082292
出版商: Taylor & Francis Group
关键词: Intervalence spectra;Vanadium prussiates;Pentacyanoferrate(II) complexes
数据来源: Taylor
摘要:
Vanadium(III) ions form with cyanoferrate(II) and cyanoruthenate(II) complexes a series of polymeric compounds displaying strong intervalence transfer bands in the visible region. The intervalence transfer energies are linearly correlated with the redox potentials of the cyanometallates, and follow very closely the corresponding data for the Prussian blue complexes.
点击下载:
PDF (283KB)
返 回