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Intervalence Transfer Spectra of Vanadium(III) Prussian Blue Complexes

 

作者: HenriqueE. Toma,   FernandoT. P. Lellis,  

 

期刊: Spectroscopy Letters  (Taylor Available online 1988)
卷期: Volume 21, issue 1  

页码: 45-54

 

ISSN:0038-7010

 

年代: 1988

 

DOI:10.1080/00387018808082292

 

出版商: Taylor & Francis Group

 

关键词: Intervalence spectra;Vanadium prussiates;Pentacyanoferrate(II) complexes

 

数据来源: Taylor

 

摘要:

Vanadium(III) ions form with cyanoferrate(II) and cyanoruthenate(II) complexes a series of polymeric compounds displaying strong intervalence transfer bands in the visible region. The intervalence transfer energies are linearly correlated with the redox potentials of the cyanometallates, and follow very closely the corresponding data for the Prussian blue complexes.

 

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