Viscoelastic properties and stability of BBL ladder polymers
作者:
Joseph W. Powell,
Richard P. Chartoff,
期刊:
Journal of Applied Polymer Science
(WILEY Available online 1974)
卷期:
Volume 18,
issue 1
页码: 83-91
ISSN:0021-8995
年代: 1974
DOI:10.1002/app.1974.070180107
出版商: Wiley Subscription Services, Inc., A Wiley Company
数据来源: WILEY
摘要:
AbstractViscoelastic properties of the BBL ladder polymer were determined by a dynamic mechanical technique for the temperature range −150°C to 250°C and at frequencies of 3.5, 11, and 110 Hz. A secondary loss dispersion centered at −50°C (at 110 Hz) was discovered which probably arises from an in‐chain relaxation mechanism. The loss dispersion resembles β‐transitions found in more conventional polymers in intensity (maximum tan δ = 0.035), activation energy(E= 19,000 cal/mole), and in its close relation to the high‐temperature mechanical properties of the polymers. Only slight changes in the low‐temperature loss peak cause significant increases in brittleness. It is proposed that such changes, produced by a variety of environments, result from random chain scission at imperfection points in the ladder structure. For this reason we conclude that improving the environmental stability of BBL is of prime importance in its further development for speci
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