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A New Technique for Auger Analysis of Surface Species Subject to Electron‐Induced Desorption

 

作者: Stephen V. Pepper,  

 

期刊: Review of Scientific Instruments  (AIP Available online 1973)
卷期: Volume 44, issue 7  

页码: 826-829

 

ISSN:0034-6748

 

年代: 1973

 

DOI:10.1063/1.1686257

 

出版商: AIP

 

数据来源: AIP

 

摘要:

A method is presented to observe surface species subject to electron‐induced desorption by Auger electron spectroscopy. The surface to be examined is moved under the electron beam at constant velocity, establishing a time‐independent condition and eliminating the time response of the electron spectrometer as a limiting factor. The dependence of the Auger signal on the sample velocity, incident electron current, beam diameter, and desorption cross section is analyzed. It is shown that it is advantageous to analyze the moving sample with a high beam current, in contrast to the usual practice of using a low beam current to minimize desorption from a stationary sample. The method is illustrated by the analysis of a friction transfer film of PTFE, in which the fluorine is removed by electron‐induced desorption. The method is relevant to surface studies in the field of lubrication and catalysis.

 

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