Liquid-Liquid Chromatographic Separation of Neodymium, Samarium, and Gadolinium
作者:
J.G. Winget,
R.E. Lindstrom,
期刊:
Separation Science
(Taylor Available online 1971)
卷期:
Volume 6,
issue 4
页码: 573-581
ISSN:0037-2366
年代: 1971
DOI:10.1080/00372367108056040
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Neodymium, samarium, and gadolinium were separated by a liquid-liquid chromatographic technique. Sulfuric acid was more effective than hydrochloric or nitric acid as an eluent with di(2-ethylhexyl) phosphoric acid (EHPA) as the stationary phase. Recovery of 45% of the neodymium as >90% Nd2O3, 84% of the samarium as>99% Sm2O3, and 50% of the gadolinium as>99% Gd2O3was achieved. The degree of separation and the time required for the separation can be varied by changing the concentration of the eluent and the number of stages in the system. A system comprising a primary amine organic extractant and an aqueous eluent containing diethylenetriaminepentaacetic acid (DTPA) was less effective for separating the rare earths.
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