Front matter

 

作者:

 

期刊: Annual Reports on the Progress of Chemistry  (RSC Available online 1959)
卷期: Volume 56, issue 1  

页码: 001-014

 

ISSN:0365-6217

 

年代: 1959

 

DOI:10.1039/AR95956FP001

 

出版商: RSC

 

数据来源: RSC

 

摘要:

REVIEWS OF BOOKS 3 649 producing the book is said by the authors to be " the fceling that our good fortune in acquiring a large mass of previously inaccessible data leaves u s with an obligation to collect this into one place for ease of access ". Certainly. to have so many spectra brought together in one volume is most valuable, the more so since many of them have not previously been published. The molecules whose spectra are presented range from triatomic to naphthalene and even bigger molecules. There are short introductory accounts of the underlying theory and of the experimental methods, but the bulk of the book is devoted to showing and interpreting the spectra, molecule by molecule. For each molecule, the full photoelectron spectrum is shown first; and then, under higher resolution, each " band " in the full spectrum.The book is intended to be a reference work for research workers. As such it will be invaluable to anyone interested in the electronic spectra of molecules and ions; and, indeed, to anyone interested in molecular orbitals, for whatever purpose. With its hundreds of excellent line drawings, the book as a whole can be said to be well produced. There are, however, signs of too hurried preparation. Thus on page 6, figs. 6.23, 6.26 and 6.27 are stated to refer to the spectra of diacetylene, cyanoacetylene and cyanogen; but in fact the figure captions make it clear that the figures refer to acetylene-d2, diacetylene and cyanoacetylene respec- tively. The text appears not to have been checked quite as carefully as it should have been.Othei errors, not entirely trivial, lead to the same conclusion. Thus (lb2)2 is written in error for (lb# (p. 78, line 7); lB1 is written in error for 2B1 (p. 77, table 4.4; p. 79, table 4.6; p. 81, table4.7); (1b)2 is in error for (lb1)2 (p. 81, line -2); v1 is in error for v2 (the bending vibration of SO,; see p. 85); and lxU is in error for lxu (p. 170). On p. 87 (line 18), nitrous oxide is writtenin error for nitrogen dioxide; NO+ is in error for NO: (line 2); and 124" is written by mistake for 134". A little more time spent on proof reading would have eliminated these and other blemishes. A. D. WALSH Received 25th June, 1971 Chemistry of Complex Equilibria. By M. T. BECK. (Van Nostrand Reinhold Co., London, 1970.) This book, one of an analytical chemistry series, has the admirable aim of giving a broad and realistic account of complex equilibria in solution in which the chemistry is not hidden behind algebraic equations.Anyone who has but glanced at the Chemical Society publication StabiZity Constants will appreciate that this is a formidable task, especially when topics such as mixed ligand, protonated and polynuclear complexes are rightly treated in some detail. Even neglecting problems concerned with the rates of attainment of equilibria, the complexity of the composition of many common and important solutions such as those of aluminium salts or of silicates in water is depressing. There are no entirely satisfactory methods of species identification, and the physical significance of the numerous equilibria which have been postulated for such systems is highly suspect.The Hungarian author has a readable style with some entertaining asides, e.g., " Rediscovery is a fairly frequent phenomenon now ", " Sometimes a linear relationship is assumed between the price of the instrument and the value of the information obtained by its means "; he has obviously actually read many of the historically important papers which he cites, and the literature references are less exclusively Anglo-Saxon than is often the case. In some places, however, references are catalogued with little evaluation. There is a curious and basically unhealthy dichotomy in the subject between those who label themselves " inorganic " or " co-ordination " chemists, who are primarily interested in speci identification and the equilibria between them, and '' physical " or " electrolyte solution " chemists who lay emphasis on the quantitative description of physicochemical properties in general.This book is of the co-ordination chemistry variety. For example, conductivity measurements are rele- gated to a reference to C. W. Davies under " miscellaneous methods", the information obtainable from osmotic coefficient measurements is only briefly mentioned in the context of some eutectic systems, and the problems which arise from lack of knowledge of ionic activity coefficients or their variations with solution composition are largely avoided. Although in the reviewer's opinion an outstanding book which treats both the methods and the results of stability constant determinations in a readable and compact manner is still to be written this is a useful attempt.Life and earth scientists who refer to it will readily appreciate the reasons for the stark contrast between the elegant simplicity of the standard text-book treatment of simple acid- base and complex-ion equilibria, and the remarkably unhelpful replies they are likely to get from chemists to questions about the chemical equilibria in physiological fluids and natural waters! Pp. 285. Price g4.50. J. E. PRUE Received 5th May, 1971REVIEWS OF BOOKS 3 649 producing the book is said by the authors to be " the fceling that our good fortune in acquiring a large mass of previously inaccessible data leaves u s with an obligation to collect this into one place for ease of access ".Certainly. to have so many spectra brought together in one volume is most valuable, the more so since many of them have not previously been published. The molecules whose spectra are presented range from triatomic to naphthalene and even bigger molecules. There are short introductory accounts of the underlying theory and of the experimental methods, but the bulk of the book is devoted to showing and interpreting the spectra, molecule by molecule. For each molecule, the full photoelectron spectrum is shown first; and then, under higher resolution, each " band " in the full spectrum. The book is intended to be a reference work for research workers. As such it will be invaluable to anyone interested in the electronic spectra of molecules and ions; and, indeed, to anyone interested in molecular orbitals, for whatever purpose.With its hundreds of excellent line drawings, the book as a whole can be said to be well produced. There are, however, signs of too hurried preparation. Thus on page 6, figs. 6.23, 6.26 and 6.27 are stated to refer to the spectra of diacetylene, cyanoacetylene and cyanogen; but in fact the figure captions make it clear that the figures refer to acetylene-d2, diacetylene and cyanoacetylene respec- tively. The text appears not to have been checked quite as carefully as it should have been. Othei errors, not entirely trivial, lead to the same conclusion. Thus (lb2)2 is written in error for (lb# (p. 78, line 7); lB1 is written in error for 2B1 (p. 77, table 4.4; p. 79, table 4.6; p. 81, table4.7); (1b)2 is in error for (lb1)2 (p.81, line -2); v1 is in error for v2 (the bending vibration of SO,; see p. 85); and lxU is in error for lxu (p. 170). On p. 87 (line 18), nitrous oxide is writtenin error for nitrogen dioxide; NO+ is in error for NO: (line 2); and 124" is written by mistake for 134". A little more time spent on proof reading would have eliminated these and other blemishes. A. D. WALSH Received 25th June, 1971 Chemistry of Complex Equilibria. By M. T. BECK. (Van Nostrand Reinhold Co., London, 1970.) This book, one of an analytical chemistry series, has the admirable aim of giving a broad and realistic account of complex equilibria in solution in which the chemistry is not hidden behind algebraic equations. Anyone who has but glanced at the Chemical Society publication StabiZity Constants will appreciate that this is a formidable task, especially when topics such as mixed ligand, protonated and polynuclear complexes are rightly treated in some detail. Even neglecting problems concerned with the rates of attainment of equilibria, the complexity of the composition of many common and important solutions such as those of aluminium salts or of silicates in water is depressing.There are no entirely satisfactory methods of species identification, and the physical significance of the numerous equilibria which have been postulated for such systems is highly suspect. The Hungarian author has a readable style with some entertaining asides, e.g., " Rediscovery is a fairly frequent phenomenon now ", " Sometimes a linear relationship is assumed between the price of the instrument and the value of the information obtained by its means "; he has obviously actually read many of the historically important papers which he cites, and the literature references are less exclusively Anglo-Saxon than is often the case.In some places, however, references are catalogued with little evaluation. There is a curious and basically unhealthy dichotomy in the subject between those who label themselves " inorganic " or " co-ordination " chemists, who are primarily interested in speci identification and the equilibria between them, and '' physical " or " electrolyte solution " chemists who lay emphasis on the quantitative description of physicochemical properties in general. This book is of the co-ordination chemistry variety.For example, conductivity measurements are rele- gated to a reference to C. W. Davies under " miscellaneous methods", the information obtainable from osmotic coefficient measurements is only briefly mentioned in the context of some eutectic systems, and the problems which arise from lack of knowledge of ionic activity coefficients or their variations with solution composition are largely avoided. Although in the reviewer's opinion an outstanding book which treats both the methods and the results of stability constant determinations in a readable and compact manner is still to be written this is a useful attempt. Life and earth scientists who refer to it will readily appreciate the reasons for the stark contrast between the elegant simplicity of the standard text-book treatment of simple acid- base and complex-ion equilibria, and the remarkably unhelpful replies they are likely to get from chemists to questions about the chemical equilibria in physiological fluids and natural waters! Pp.285. Price g4.50. J. E. PRUE Received 5th May, 1971REVIEWS OF BOOKS 3 649 producing the book is said by the authors to be " the fceling that our good fortune in acquiring a large mass of previously inaccessible data leaves u s with an obligation to collect this into one place for ease of access ". Certainly. to have so many spectra brought together in one volume is most valuable, the more so since many of them have not previously been published. The molecules whose spectra are presented range from triatomic to naphthalene and even bigger molecules.There are short introductory accounts of the underlying theory and of the experimental methods, but the bulk of the book is devoted to showing and interpreting the spectra, molecule by molecule. For each molecule, the full photoelectron spectrum is shown first; and then, under higher resolution, each " band " in the full spectrum. The book is intended to be a reference work for research workers. As such it will be invaluable to anyone interested in the electronic spectra of molecules and ions; and, indeed, to anyone interested in molecular orbitals, for whatever purpose. With its hundreds of excellent line drawings, the book as a whole can be said to be well produced. There are, however, signs of too hurried preparation. Thus on page 6, figs.6.23, 6.26 and 6.27 are stated to refer to the spectra of diacetylene, cyanoacetylene and cyanogen; but in fact the figure captions make it clear that the figures refer to acetylene-d2, diacetylene and cyanoacetylene respec- tively. The text appears not to have been checked quite as carefully as it should have been. Othei errors, not entirely trivial, lead to the same conclusion. Thus (lb2)2 is written in error for (lb# (p. 78, line 7); lB1 is written in error for 2B1 (p. 77, table 4.4; p. 79, table 4.6; p. 81, table4.7); (1b)2 is in error for (lb1)2 (p. 81, line -2); v1 is in error for v2 (the bending vibration of SO,; see p. 85); and lxU is in error for lxu (p. 170). On p. 87 (line 18), nitrous oxide is writtenin error for nitrogen dioxide; NO+ is in error for NO: (line 2); and 124" is written by mistake for 134".A little more time spent on proof reading would have eliminated these and other blemishes. A. D. WALSH Received 25th June, 1971 Chemistry of Complex Equilibria. By M. T. BECK. (Van Nostrand Reinhold Co., London, 1970.) This book, one of an analytical chemistry series, has the admirable aim of giving a broad and realistic account of complex equilibria in solution in which the chemistry is not hidden behind algebraic equations. Anyone who has but glanced at the Chemical Society publication StabiZity Constants will appreciate that this is a formidable task, especially when topics such as mixed ligand, protonated and polynuclear complexes are rightly treated in some detail.Even neglecting problems concerned with the rates of attainment of equilibria, the complexity of the composition of many common and important solutions such as those of aluminium salts or of silicates in water is depressing. There are no entirely satisfactory methods of species identification, and the physical significance of the numerous equilibria which have been postulated for such systems is highly suspect. The Hungarian author has a readable style with some entertaining asides, e.g., " Rediscovery is a fairly frequent phenomenon now ", " Sometimes a linear relationship is assumed between the price of the instrument and the value of the information obtained by its means "; he has obviously actually read many of the historically important papers which he cites, and the literature references are less exclusively Anglo-Saxon than is often the case.In some places, however, references are catalogued with little evaluation. There is a curious and basically unhealthy dichotomy in the subject between those who label themselves " inorganic " or " co-ordination " chemists, who are primarily interested in speci identification and the equilibria between them, and '' physical " or " electrolyte solution " chemists who lay emphasis on the quantitative description of physicochemical properties in general. This book is of the co-ordination chemistry variety. For example, conductivity measurements are rele- gated to a reference to C. W. Davies under " miscellaneous methods", the information obtainable from osmotic coefficient measurements is only briefly mentioned in the context of some eutectic systems, and the problems which arise from lack of knowledge of ionic activity coefficients or their variations with solution composition are largely avoided.Although in the reviewer's opinion an outstanding book which treats both the methods and the results of stability constant determinations in a readable and compact manner is still to be written this is a useful attempt. Life and earth scientists who refer to it will readily appreciate the reasons for the stark contrast between the elegant simplicity of the standard text-book treatment of simple acid- base and complex-ion equilibria, and the remarkably unhelpful replies they are likely to get from chemists to questions about the chemical equilibria in physiological fluids and natural waters! Pp. 285.Price g4.50. J. E. PRUE Received 5th May, 1971CO MPE TE L Y NEW RE VIS ED AND RE-SET EDIT10N MODERN ASPECTS OF INORGANIC CHEMISTRY by H. J. Emeleus, D.Sc., A.R.C.S., F.R.S. *PROFESSOR OF INORGANIC CHEMISTRY, UNIVERSITY OF CAMBRIDGE) and J. S. Anderson, Ph.D., A.R.C.S., F.R.S. (DIRECTOR, NATl ONAL CHEMICAL LABORATORY) In preparing the third edition of this book the authors have attempted to make the subject matter reflect the present state of knowledge and the most important developments in inorganic chemistry. The choice of topics for discussion is necessarily somewhat arbitrary. Furthermore, some fields of inorganic chemical research -for example boron chemistry, the theory of co-ordination compounds, organometallic chemistry -are so productive of new knowledge that it is impossible to do full justice to recent progress in the whole subject.Nevertheless, it is hoped that this new edition will give the reader some picture of developments during recent years in our knowledge, our theoretical outlook and our understanding of the chemistry of the elements. The authors ask that the book be read critically, and that where possible the text should be supplemented by reference to the more important original papers. The book is written primarily for Honours students, research workers and teachers, but will also interest the Scholarship candidate in schools. 35s. ROUTLEDGE & KEGAN PAUL ivCO MPE TE L Y NEW RE VIS ED AND RE-SET EDIT10N MODERN ASPECTS OF INORGANIC CHEMISTRY by H.J. Emeleus, D.Sc., A.R.C.S., F.R.S. *PROFESSOR OF INORGANIC CHEMISTRY, UNIVERSITY OF CAMBRIDGE) and J. S. Anderson, Ph.D., A.R.C.S., F.R.S. (DIRECTOR, NATl ONAL CHEMICAL LABORATORY) In preparing the third edition of this book the authors have attempted to make the subject matter reflect the present state of knowledge and the most important developments in inorganic chemistry. The choice of topics for discussion is necessarily somewhat arbitrary. Furthermore, some fields of inorganic chemical research -for example boron chemistry, the theory of co-ordination compounds, organometallic chemistry -are so productive of new knowledge that it is impossible to do full justice to recent progress in the whole subject. Nevertheless, it is hoped that this new edition will give the reader some picture of developments during recent years in our knowledge, our theoretical outlook and our understanding of the chemistry of the elements.The authors ask that the book be read critically, and that where possible the text should be supplemented by reference to the more important original papers. The book is written primarily for Honours students, research workers and teachers, but will also interest the Scholarship candidate in schools. 35s. ROUTLEDGE & KEGAN PAUL ivIntroducing an important and authoritative encyclopedia THE INTERNATIONAL ENCYCLOPEDIA OF PHYSICAL CHEMISTRY AND CHEMICAL PHYSICS Editors-in-Chief E. A. GUGGENHEIM J. E. MAYER F. C. TOMPKINS The International Encyclopedia of Physical Chemistry a d Chemical Physics will be an authoritative and comprehensive presentation of the domaln of knowledge which lies between and overlaps chemistry and physics.Each volume--between 50 and 100 volumes are planned-will be written primarily for the physical chemist and chemical physicist, but many volumes will be of value to other scientists. The volumes will be grouped into topics, as follows: I. 2. 3. 4. 5. 6. 7. 8. 9. lo. I I. MATHEMATICAL TECH NlQUES Editor: H. JONES CLASSICAL AND QUANTUM MECHANICS Editor: PER-OLOF LOWDIN ELECTRONIC STRUCTURE OF Editor: CLYDE HUTCHISON, Jr. MOLECULAR BINDING Editor being appointed MOLECULAR PROPERTIES ATOMS (a) Electronic ( b ) Non-electronic Editors being appointed KINETIC THEORY OF GASES Editor: E. A. GUGGENHEIM CLASSICAL THERMODYNAMICS Editor: D.H. EVERETT STATISTICAL MECHANICS Editor: J. E. MAYER TRANSPORT PHENOMENA Editor: J. E. MAYER THE FLUID STATE Editor: J. S. ROWLINSON THE IDEAL CRYSTALLINE STATE Editor: M. BLACKMAN 12. IMPERFECTIONS IN SOLIDS Editor: A. B. LlDlARD 13. MIXTURES, SOLUTIONS, CHEMI- CAL AND PHASE EQUILIBRIA Editor: M. L. MeGLASHAN 14. PROPERTIES OF INTERFACES 15. EQUILIBRIUM PROPERTIES OF Editor: D. H. EVERETT ELECTROLYTE SOLUTIONS 16. TRANSPORT PROPERTIES OF Editor: R. A. ROBINSON ELECTROLYTES Editor: R. H. STOKES 17. MACROMOLECULES 18. 19. 20. 21. 22. Editor: C. E. H. BAWN DIELECTRIC AND MAGNETIC PRO PE RTI ES Editor: WILLARD STO UT GAS KINETICS Editor: A. TROTMA N-DICKE NSO N SO LUTl ON KI NET1 CS Editor: R. M. NOYES SOLID AND SURFACE KINETICS Editor: F. C. TOMPKINS RADIATION CHEMISTRY Editor: ROBERT LIVINGSTON lust published in Topic 6 Volume I ELEMENTS OF THE KINETIC THEORY OF GASES by E.A. GUGGENHEIM, M.A., Sc.D., F.R.S. This volume describes in an elementary way the most important features of the kinetic theory ofgases. and as such will prove most useful to physical chemists and chemical physicists who would not norm- ally have a standard of mathematics necessary for the more advanced treatments. 17s 6d net ($3.00) Write now for details of this outstanding encyclopedia Headington Hill Hall, Oxford 4 & 5 fitzroy Square, London W. I 122 East 55th Street, New York 22, M Y .Introducing an important and authoritative encyclopedia THE INTERNATIONAL ENCYCLOPEDIA OF PHYSICAL CHEMISTRY AND CHEMICAL PHYSICS Editors-in-Chief E.A. GUGGENHEIM J. E. MAYER F. C. TOMPKINS The International Encyclopedia of Physical Chemistry a d Chemical Physics will be an authoritative and comprehensive presentation of the domaln of knowledge which lies between and overlaps chemistry and physics. Each volume--between 50 and 100 volumes are planned-will be written primarily for the physical chemist and chemical physicist, but many volumes will be of value to other scientists. The volumes will be grouped into topics, as follows: I. 2. 3. 4. 5. 6. 7. 8. 9. lo. I I. MATHEMATICAL TECH NlQUES Editor: H. JONES CLASSICAL AND QUANTUM MECHANICS Editor: PER-OLOF LOWDIN ELECTRONIC STRUCTURE OF Editor: CLYDE HUTCHISON, Jr. MOLECULAR BINDING Editor being appointed MOLECULAR PROPERTIES ATOMS (a) Electronic ( b ) Non-electronic Editors being appointed KINETIC THEORY OF GASES Editor: E.A. GUGGENHEIM CLASSICAL THERMODYNAMICS Editor: D. H. EVERETT STATISTICAL MECHANICS Editor: J. E. MAYER TRANSPORT PHENOMENA Editor: J. E. MAYER THE FLUID STATE Editor: J. S. ROWLINSON THE IDEAL CRYSTALLINE STATE Editor: M. BLACKMAN 12. IMPERFECTIONS IN SOLIDS Editor: A. B. LlDlARD 13. MIXTURES, SOLUTIONS, CHEMI- CAL AND PHASE EQUILIBRIA Editor: M. L. MeGLASHAN 14. PROPERTIES OF INTERFACES 15. EQUILIBRIUM PROPERTIES OF Editor: D. H. EVERETT ELECTROLYTE SOLUTIONS 16. TRANSPORT PROPERTIES OF Editor: R. A. ROBINSON ELECTROLYTES Editor: R. H. STOKES 17. MACROMOLECULES 18. 19. 20. 21. 22. Editor: C. E. H. BAWN DIELECTRIC AND MAGNETIC PRO PE RTI ES Editor: WILLARD STO UT GAS KINETICS Editor: A. TROTMA N-DICKE NSO N SO LUTl ON KI NET1 CS Editor: R.M. NOYES SOLID AND SURFACE KINETICS Editor: F. C. TOMPKINS RADIATION CHEMISTRY Editor: ROBERT LIVINGSTON lust published in Topic 6 Volume I ELEMENTS OF THE KINETIC THEORY OF GASES by E. A. GUGGENHEIM, M.A., Sc.D., F.R.S. This volume describes in an elementary way the most important features of the kinetic theory ofgases. and as such will prove most useful to physical chemists and chemical physicists who would not norm- ally have a standard of mathematics necessary for the more advanced treatments. 17s 6d net ($3.00) Write now for details of this outstanding encyclopedia Headington Hill Hall, Oxford 4 & 5 fitzroy Square, London W. I 122 East 55th Street, New York 22, M Y .: a mama a a am a a a chemical nomenclature *arn: i Introduction to Chemical Nomenclature i a a a a a : By R.S. CAHN, M.A., Dr.PhiI.Nat., F.R.I.C., Editor to the Chemical : : Society, London. Price 10s. 6d. : a : A description of the principles of chemical nomenclature, particularly of modern systematic nomenclature as accepted by The Chemical Society of London. Con- : : tents include: The Use and Misuse of Nomenclature. Inorganic Nomenclature. : Organic Nomenclature: General; The Principal Functional Group; Numbering; a : Building a Name; Skeletal Types; Some Special Cases. Physico-Chemical Symbols. : : ‘ I Remarkably clear and concise . . . provides some very helpful guiding rules. So : : much information is packed into its 90-odd pages . . . all chemists can aflord to pur- : : chase (the book); they cannot aflord to do otherwise.” a -Journal of the Royal Institute of Chemistry : a a a a a a a a Nomenclature of j Nomenclature of a i Organic Chemistry Inorganic Chemistry i : IUPAC 1957 RULES. Issued by the International Union of Pure and : : Applied Chemistry.Price 15s. each. i : One of the outstanding problems in chemistry is the naming of chemical com- : pounds. At last some order has been introduced by IUPAC, whose Committees a have formulated rules acceptable as a basis to chemists throughout the world. : a m “A real contribution towards technical progress . . . unhesitatingly recommended. . . a : should be read and kept as a reference andguide for all (Chemistry) workers.” a m a a m i am a a am a a a BUTTERWORTHS a ma a a a a am a a a a a i -Transactions of the Plastics Institute ~ F o DARTON & Coo LTDo WATFORD HERTS a ENGLAND ESTABLISHED 1834 THERMOGRAPHS HYGROGRAPHS BAROGRAPHS Makers of KEW PAlTERN BAROMETERS FORTI N BAROMETERS HY GROM ETE RS MAN OM ETE RS / REGISTERED \ I R A Q I MARK ALTl METER CALI BRATORS viiiTHE CHEMICAL SUPPLY CO LTD for details of the many new products they are manufacturing Ester Solvents Alkyl & Aryl Ester PIasticisers Formaldehyde & Hexamine Special Plastic Grades Cadmium Colours Aromatic Chemicals Molybdic Products Copper Fungicides Full technical details and samples will be sent on request THE CHEMICAL SUPPLY CO LTD 7 IDOL LANE, EASTCHEAP, LONDON EC3 Tel: Mansion House 6854 Gram: Kemsupply, Phone, London ixTHE CHEMICAL SUPPLY CO LTD for details of the many new products they are manufacturing Ester Solvents Alkyl & Aryl Ester PIasticisers Formaldehyde & Hexamine Special Plastic Grades Cadmium Colours Aromatic Chemicals Molybdic Products Copper Fungicides Full technical details and samples will be sent on request THE CHEMICAL SUPPLY CO LTD 7 IDOL LANE, EASTCHEAP, LONDON EC3 Tel: Mansion House 6854 Gram: Kemsupply, Phone, London ixTHE CHEMICAL SUPPLY CO LTD for details of the many new products they are manufacturing Ester Solvents Alkyl & Aryl Ester PIasticisers Formaldehyde & Hexamine Special Plastic Grades Cadmium Colours Aromatic Chemicals Molybdic Products Copper Fungicides Full technical details and samples will be sent on request THE CHEMICAL SUPPLY CO LTD 7 IDOL LANE, EASTCHEAP, LONDON EC3 Tel: Mansion House 6854 Gram: Kemsupply, Phone, London ixL. LIGHT & CO.LTD. COLNBROOKm BUCKS ENGLAND I I I/ 999 Annual Reports on the Progress of Chemistry Back Numbers (less certain volumes now out of.print) 999 I ELEMENTS + COMPOUNDS 99-99 % to 99.9999 yo SPECTROSCOPIC CERTIFICATE SUPPLIED Collective Index of Volumes I to XLVI Inquiries are invited by: TEE CHEMICAL SOCIETY Burbgton House . London, W.lElectrons and Phonons The Theory of Transport Phenomena in Solids J. M. ZIMAN This treatise on the theory of eIectrica1 and thermal conduction in metals, semi-conductors, and insulators is written for graduate students and research workers. It gives an account of the experi- mental facts and their theoretical explanation, and the basic ideas of lattice dynamics, electron zone structure, and transport theory are developed from first principles (International Series of Mono- graphs on Physics). Text-figures 84s net Data for Biochemical Research Edited by R.M. C. DAWSON, DAPHNE C.ELLIOTT, W. H. ELLIO.TT, and K. M. 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WHEATLEY This book discusses the main physicochemical methods used to determine molecular structure. The scope and limitations of each pethod are emphasized and examples drawn from original papers. . . . will undoubtedly be of great value to first-year university students and should stimulate them to read more advanced texts to which many references are given.’ JOURNAL OF THE ROYAL INSTITUTE OF CHEMISTRY Text-figures 35s net OXFORD UNIVERSITY PRESS - xiiiApplied Pe tr o le urn Reservoir Engineering B.C. CRAFT & M. F. HAWKINS, JR. The growth of the petroleum industry demands improved scientific methods for the analysis and prediction of oil reservoir and well performance. This book is a significant contribution to this subject, which now constitutes a well- defined, highly technical branch of petroleum engineering. Med. 8vo. 437 pages. Illustrated. 62s. 6d. Fundamentals of Chemical Engineering Operations M. G. LARIAN A textbook which covers the most important elements of a wide subject concisely and on a level suitable for under- graduate instruction.Med. 8vo. 644 pages. Illustrated. 62s. 6d. Soil Chemical Analysis M. L. JACKSON This book gives the most frequently used soil chemical analysis procedures, useful in instruction and research in soil chemistry, soil fertility and soil genesis. Because plant growth is essentially related to these fields, procedures are given for plant inorganic constituents. Med. 8vo. 498 pages. Illustrated. 57s. 6d. Electrochemical Processes in Chemical Industries A. REGNER The theoretical part of this book deals with basic laws; goes on to discuss electrolytic conductance and various types of galvanic cells and concludes with a section on electrolysis and polarization. The second part deals with industrial applications. Ex. Cr. 8vo. 464pages. 149 figures. 1957. 30s. Chemical Engineering Operations: An Intro- duction to the Study of Chemical Plant F.RUMFORD Second edition. Demy 8vo. 387 pages. Illustrated. 1957. 32s. 68. Chemical Engineering Materials F. RUMFORD A major change in this second edition is the complete re- writing of the chapter on plastics as a material for use in Second edition. Demy 8vo. 400 pages. Illustrated. 32s. 6d. ' chemical plant. CONSTABLE 8~ CO. LTD 10 ORANGE STREET, LONDON, W.C.2 xivCO MPE TE L Y NEW RE VIS EDAND RE-SET EDIT10NMODERN ASPECTS OFINORGANIC CHEMISTRYby H. J. Emeleus, D.Sc., A.R.C.S., F.R.S.*PROFESSOR OF INORGANIC CHEMISTRY, UNIVERSITY OF CAMBRIDGE)and J. S. Anderson, Ph.D., A.R.C.S., F.R.S.(DIRECTOR, NATl ONAL CHEMICAL LABORATORY)In preparing the third edition of this bookthe authors have attempted to make the subject matterreflect the present state of knowledge andthe most important developments in inorganic chemistry.The choice of topics for discussionis necessarily somewhat arbitrary.Furthermore, some fields of inorganic chemical research-for example boron chemistry, the theoryof co-ordination compounds, organometallic chemistry-are so productive of new knowledgethat it is impossible to do full justiceto recent progress in the whole subject.Nevertheless, it is hoped that this new editionwill give the reader some picture of developmentsduring recent years in our knowledge,our theoretical outlook and our understandingof the chemistry of the elements.The authors ask that the book be read critically,and that where possible the text should be supplementedby reference to the more important original papers.The book is written primarily for Honours students,research workers and teachers,but will also interest the Scholarship candidate in schools.35s.ROUTLEDGE & KEGAN PAULiIntroducing an important and authoritative encyclopediaTHE INTERNATIONAL ENCYCLOPEDIA OFPHYSICAL CHEMISTRY AND CHEMICAL PHYSICSEditors-in-ChiefE. A.GUGGENHEIM J. E. MAYER F. C. TOMPKINSThe International Encyclopedia of Physical Chemistry a d Chemical Physicswill be an authoritative and comprehensive presentation of thedomaln of knowledge which lies between and overlaps chemistry andphysics.Each volume--between 50 and 100 volumes are planned-will bewritten primarily for the physical chemist and chemical physicist, butmany volumes will be of value to other scientists.The volumes will be grouped into topics, as follows:I.2.3.4.5.6.7.8.9.lo.I I.MATHEMATICAL TECH NlQUESEditor: H.JONESCLASSICAL AND QUANTUMMECHANICSEditor: PER-OLOF LOWDINELECTRONIC STRUCTURE OFEditor: CLYDE HUTCHISON, Jr.MOLECULAR BINDINGEditor being appointedMOLECULAR PROPERTIESATOMS(a) Electronic( b ) Non-electronicEditors being appointedKINETIC THEORY OF GASESEditor: E. A. GUGGENHEIMCLASSICAL THERMODYNAMICSEditor: D. H. EVERETTSTATISTICAL MECHANICSEditor: J. E. MAYERTRANSPORT PHENOMENAEditor: J. E. MAYERTHE FLUID STATEEditor: J. S. ROWLINSONTHE IDEAL CRYSTALLINE STATEEditor: M.BLACKMAN12. IMPERFECTIONS IN SOLIDSEditor: A. B. LlDlARD13. MIXTURES, SOLUTIONS, CHEMI-CAL AND PHASE EQUILIBRIAEditor: M. L. MeGLASHAN14. PROPERTIES OF INTERFACES15. EQUILIBRIUM PROPERTIES OFEditor: D. H. EVERETTELECTROLYTE SOLUTIONS16. TRANSPORT PROPERTIES OFEditor: R. A. ROBINSONELECTROLYTESEditor: R. H. STOKES17. MACROMOLECULES18.19.20.21.22.Editor: C. E. H. BAWNDIELECTRIC AND MAGNETICPRO PE RTI ESEditor: WILLARD STO UTGAS KINETICSEditor: A. TROTMA N-DICKE NSO NSO LUTl ON KI NET1 CSEditor: R. M. NOYESSOLID AND SURFACE KINETICSEditor: F. C. TOMPKINSRADIATION CHEMISTRYEditor: ROBERT LIVINGSTONlust published in Topic 6Volume IELEMENTS OF THE KINETIC THEORY OF GASESby E. A. GUGGENHEIM, M.A., Sc.D., F.R.S.This volume describes in an elementary way the most important features of the kinetic theory ofgases.and as such will prove most useful to physical chemists and chemical physicists who would not norm-ally have a standard of mathematics necessary for the more advanced treatments.17s 6d net ($3.00)Write now for details of this outstanding encyclopediaHeadington Hill Hall, Oxford 4 & 5 fitzroy Square, London W.I122 East 55th Street, New York 22, M Y : a mama a a am a a a chemical nomenclature *arn:i Introduction to Chemical Nomenclature iaa aaa : By R. S. CAHN, M.A., Dr.PhiI.Nat., F.R.I.C., Editor to the Chemical : : Society, London. Price 10s. 6d. : a : A description of the principles of chemical nomenclature, particularly of modernsystematic nomenclature as accepted by The Chemical Society of London.Con- : : tents include: The Use and Misuse of Nomenclature. Inorganic Nomenclature. :Organic Nomenclature: General; The Principal Functional Group; Numbering; a : Building a Name; Skeletal Types; Some Special Cases. Physico-Chemical Symbols. :: ‘ I Remarkably clear and concise . . . provides some very helpful guiding rules. So : : much information is packed into its 90-odd pages . . . all chemists can aflord to pur- :: chase (the book); they cannot aflord to do otherwise.” a-Journal of the Royal Institute of Chemistry : aaa aa aaa Nomenclature of j Nomenclature of a i Organic Chemistry Inorganic Chemistry i: IUPAC 1957 RULES. Issued by the International Union of Pure and :: Applied Chemistry.Price 15s. each. i: One of the outstanding problems in chemistry is the naming of chemical com- : pounds. At last some order has been introduced by IUPAC, whose Committeesa have formulated rules acceptable as a basis to chemists throughout the world. : am “A real contribution towards technical progress . . . unhesitatingly recommended. . . a : should be read and kept as a reference andguide for all (Chemistry) workers.” am a am i am a a am a a a BUTTERWORTHS a ma a a a a am a a a a a i-Transactions of the Plastics Institute~F o DARTON & Coo LTDoWATFORD HERTS a ENGLANDESTABLISHED 1834THERMOGRAPHSHYGROGRAPHSBAROGRAPHSMakers ofKEW PAlTERN BAROMETERSFORTI N BAROMETERSHY GROM ETE RSMAN OM ETE RS/ REGISTERED \I R A Q I MARKALTl METER CALI BRATORSviiTHE CHEMICAL SUPPLY CO LTDfor details of the many new productsthey are manufacturingEster SolventsAlkyl & Aryl Ester PIasticisersFormaldehyde & HexamineSpecial Plastic GradesCadmium ColoursAromatic ChemicalsMolybdic ProductsCopper FungicidesFull technical details and sampleswill be sent on requestTHE CHEMICAL SUPPLY CO LTD7 IDOL LANE, EASTCHEAP, LONDON EC3Tel: Mansion House 6854Gram: Kemsupply, Phone, LondoniL.LIGHT & CO. LTD.COLNBROOKm BUCKS ENGLANDII I/999Annual Reports on theProgress of ChemistryBack Numbers (less certain volumes now out of.print)999IELEMENTS + COMPOUNDS99-99 % to 99.9999 yoSPECTROSCOPIC CERTIFICATE SUPPLIEDCollective Index of Volumes I to XLVIInquiries are invited by:TEECHEMICALSOCIETYBurbgton House .London, W.Electrons and PhononsThe Theory of Transport Phenomena in SolidsJ. M. ZIMANThis treatise on the theory of eIectrica1 and thermal conduction inmetals, semi-conductors, and insulators is written for graduatestudents and research workers. It gives an account of the experi-mental facts and their theoretical explanation, and the basic ideasof lattice dynamics, electron zone structure, and transport theoryare developed from first principles (International Series of Mono-graphs on Physics). Text-figures 84s netData for Biochemical ResearchEdited by R. M. C. DAWSON, DAPHNEC.ELLIOTT, W. H. ELLIO.TT, and K. M. JONES‘.. . has more importance than the intrinsic value of the informa-tion it carries. Its very existence illustrates in a lively fashion theevolution from qualitative to quantitative science that is rapidlytaking place in the still young but vigorously developing subject ofbiochemistry.’ NEW SCIENTIST Text-figures 63s netExperimental Techniques in Low-Temperature PhysicsGUY KENDALL WHITE‘. . . the first of its kind in being wholly given over to the tech-niques of low temperature work, and it will meet a long-felt need.Research students just starting such work and those peoplewishing to extend investigations over a wider temperature rangewill find this publication timely and of great help. . . . Theestablished worker in the field will also find much of value in thisbook.’ BRITISH JOURNAL OF APPLIED PHYSICS (Monographs on thePhysics and Chemistry of Materials).Plates and text-figures 45s netDetermination of Molecular StructureP. J. WHEATLEYThis book discusses the main physicochemical methods used todetermine molecular structure. The scope and limitations of eachpethod are emphasized and examples drawn from original papers. . . . will undoubtedly be of great value to first-year universitystudents and should stimulate them to read more advanced textsto which many references are given.’ JOURNAL OF THE ROYALINSTITUTE OF CHEMISTRY Text-figures 35s netOXFORD UNIVERSITY PRESS-xiiApplied Pe tr o le urn Reservoir EngineeringB. C. CRAFT & M. F. HAWKINS, JR.The growth of the petroleum industry demands improvedscientific methods for the analysis and prediction of oilreservoir and well performance.This book is a significantcontribution to this subject, which now constitutes a well-defined, highly technical branch of petroleum engineering.Med. 8vo. 437 pages. Illustrated. 62s. 6d.Fundamentals of Chemical EngineeringOperationsM. G. LARIANA textbook which covers the most important elements of awide subject concisely and on a level suitable for under-graduate instruction.Med. 8vo. 644 pages. Illustrated. 62s. 6d.Soil Chemical AnalysisM. L. JACKSONThis book gives the most frequently used soil chemicalanalysis procedures, useful in instruction and research in soilchemistry, soil fertility and soil genesis.Because plantgrowth is essentially related to these fields, procedures aregiven for plant inorganic constituents.Med. 8vo. 498 pages. Illustrated. 57s. 6d.Electrochemical Processes in ChemicalIndustriesA. REGNERThe theoretical part of this book deals with basic laws; goeson to discuss electrolytic conductance and various types ofgalvanic cells and concludes with a section on electrolysisand polarization. The second part deals with industrialapplications.Ex. Cr. 8vo. 464pages. 149 figures. 1957. 30s.Chemical Engineering Operations: An Intro-duction to the Study of Chemical PlantF. RUMFORDSecond edition. Demy 8vo. 387 pages. Illustrated. 1957.32s. 68.Chemical Engineering MaterialsF. RUMFORDA major change in this second edition is the complete re-writing of the chapter on plastics as a material for use inSecond edition.Demy 8vo. 400 pages. Illustrated. 32s. 6d.' chemical plant.CONSTABLE 8~ CO. LTD10 ORANGE STREET, LONDON, W.C.2xiCO MPE TE L Y NEW RE VIS EDAND RE-SET EDIT10NMODERN ASPECTS OFINORGANIC CHEMISTRYby H. J. Emeleus, D.Sc., A.R.C.S., F.R.S.*PROFESSOR OF INORGANIC CHEMISTRY, UNIVERSITY OF CAMBRIDGE)and J. S. Anderson, Ph.D., A.R.C.S., F.R.S.(DIRECTOR, NATl ONAL CHEMICAL LABORATORY)In preparing the third edition of this bookthe authors have attempted to make the subject matterreflect the present state of knowledge andthe most important developments in inorganic chemistry.The choice of topics for discussionis necessarily somewhat arbitrary.Furthermore, some fields of inorganic chemical research-for example boron chemistry, the theoryof co-ordination compounds, organometallic chemistry-are so productive of new knowledgethat it is impossible to do full justiceto recent progress in the whole subject.Nevertheless, it is hoped that this new editionwill give the reader some picture of developmentsduring recent years in our knowledge,our theoretical outlook and our understandingof the chemistry of the elements.The authors ask that the book be read critically,and that where possible the text should be supplementedby reference to the more important original papers.The book is written primarily for Honours students,research workers and teachers,but will also interest the Scholarship candidate in schools.35s.ROUTLEDGE & KEGAN PAULiIntroducing an important and authoritative encyclopediaTHE INTERNATIONAL ENCYCLOPEDIA OFPHYSICAL CHEMISTRY AND CHEMICAL PHYSICSEditors-in-ChiefE. A.GUGGENHEIM J. E. MAYER F. C. TOMPKINSThe International Encyclopedia of Physical Chemistry a d Chemical Physicswill be an authoritative and comprehensive presentation of thedomaln of knowledge which lies between and overlaps chemistry andphysics.Each volume--between 50 and 100 volumes are planned-will bewritten primarily for the physical chemist and chemical physicist, butmany volumes will be of value to other scientists.The volumes will be grouped into topics, as follows:I.2.3.4.5.6.7.8.9.lo.I I.MATHEMATICAL TECH NlQUESEditor: H.JONESCLASSICAL AND QUANTUMMECHANICSEditor: PER-OLOF LOWDINELECTRONIC STRUCTURE OFEditor: CLYDE HUTCHISON, Jr.MOLECULAR BINDINGEditor being appointedMOLECULAR PROPERTIESATOMS(a) Electronic( b ) Non-electronicEditors being appointedKINETIC THEORY OF GASESEditor: E. A. GUGGENHEIMCLASSICAL THERMODYNAMICSEditor: D. H. EVERETTSTATISTICAL MECHANICSEditor: J. E. MAYERTRANSPORT PHENOMENAEditor: J. E. MAYERTHE FLUID STATEEditor: J. S. ROWLINSONTHE IDEAL CRYSTALLINE STATEEditor: M. BLACKMAN12. IMPERFECTIONS IN SOLIDSEditor: A. B. LlDlARD13. MIXTURES, SOLUTIONS, CHEMI-CAL AND PHASE EQUILIBRIAEditor: M. L. MeGLASHAN14. PROPERTIES OF INTERFACES15. EQUILIBRIUM PROPERTIES OFEditor: D.H. EVERETTELECTROLYTE SOLUTIONS16. TRANSPORT PROPERTIES OFEditor: R. A. ROBINSONELECTROLYTESEditor: R. H. STOKES17. MACROMOLECULES18.19.20.21.22.Editor: C. E. H. BAWNDIELECTRIC AND MAGNETICPRO PE RTI ESEditor: WILLARD STO UTGAS KINETICSEditor: A. TROTMA N-DICKE NSO NSO LUTl ON KI NET1 CSEditor: R. M. NOYESSOLID AND SURFACE KINETICSEditor: F. C. TOMPKINSRADIATION CHEMISTRYEditor: ROBERT LIVINGSTONlust published in Topic 6Volume IELEMENTS OF THE KINETIC THEORY OF GASESby E. A. GUGGENHEIM, M.A., Sc.D., F.R.S.This volume describes in an elementary way the most important features of the kinetic theory ofgases.and as such will prove most useful to physical chemists and chemical physicists who would not norm-ally have a standard of mathematics necessary for the more advanced treatments.17s 6d net ($3.00)Write now for details of this outstanding encyclopediaHeadington Hill Hall, Oxford 4 & 5 fitzroy Square, London W.I122 East 55th Street, New York 22, M Y : a mama a a am a a a chemical nomenclature *arn:i Introduction to Chemical Nomenclature iaa aaa : By R. S. CAHN, M.A., Dr.PhiI.Nat., F.R.I.C., Editor to the Chemical : : Society, London. Price 10s. 6d. : a : A description of the principles of chemical nomenclature, particularly of modernsystematic nomenclature as accepted by The Chemical Society of London. Con- : : tents include: The Use and Misuse of Nomenclature. Inorganic Nomenclature. :Organic Nomenclature: General; The Principal Functional Group; Numbering; a : Building a Name; Skeletal Types; Some Special Cases.Physico-Chemical Symbols. :: ‘ I Remarkably clear and concise . . . provides some very helpful guiding rules. So : : much information is packed into its 90-odd pages . . . all chemists can aflord to pur- :: chase (the book); they cannot aflord to do otherwise.” a-Journal of the Royal Institute of Chemistry : aaa aa aaa Nomenclature of j Nomenclature of a i Organic Chemistry Inorganic Chemistry i: IUPAC 1957 RULES. Issued by the International Union of Pure and :: Applied Chemistry. Price 15s. each. i: One of the outstanding problems in chemistry is the naming of chemical com- : pounds. At last some order has been introduced by IUPAC, whose Committeesa have formulated rules acceptable as a basis to chemists throughout the world.: am “A real contribution towards technical progress . . . unhesitatingly recommended. . . a : should be read and kept as a reference andguide for all (Chemistry) workers.” am a am i am a a am a a a BUTTERWORTHS a ma a a a a am a a a a a i-Transactions of the Plastics Institute~F o DARTON & Coo LTDoWATFORD HERTS a ENGLANDESTABLISHED 1834THERMOGRAPHSHYGROGRAPHSBAROGRAPHSMakers ofKEW PAlTERN BAROMETERSFORTI N BAROMETERSHY GROM ETE RSMAN OM ETE RS/ REGISTERED \I R A Q I MARKALTl METER CALI BRATORSviiTHE CHEMICAL SUPPLY CO LTDfor details of the many new productsthey are manufacturingEster SolventsAlkyl & Aryl Ester PIasticisersFormaldehyde & HexamineSpecial Plastic GradesCadmium ColoursAromatic ChemicalsMolybdic ProductsCopper FungicidesFull technical details and sampleswill be sent on requestTHE CHEMICAL SUPPLY CO LTD7 IDOL LANE, EASTCHEAP, LONDON EC3Tel: Mansion House 6854Gram: Kemsupply, Phone, LondoniL.LIGHT & CO. LTD.COLNBROOKm BUCKS ENGLANDII I/999Annual Reports on theProgress of ChemistryBack Numbers (less certain volumes now out of.print)999IELEMENTS + COMPOUNDS99-99 % to 99.9999 yoSPECTROSCOPIC CERTIFICATE SUPPLIEDCollective Index of Volumes I to XLVIInquiries are invited by:TEECHEMICALSOCIETYBurbgton House . London, W.Electrons and PhononsThe Theory of Transport Phenomena in SolidsJ. M. ZIMANThis treatise on the theory of eIectrica1 and thermal conduction inmetals, semi-conductors, and insulators is written for graduatestudents and research workers.It gives an account of the experi-mental facts and their theoretical explanation, and the basic ideasof lattice dynamics, electron zone structure, and transport theoryare developed from first principles (International Series of Mono-graphs on Physics). Text-figures 84s netData for Biochemical ResearchEdited by R. M. C. DAWSON, DAPHNEC.ELLIOTT, W. H. ELLIO.TT, and K. M. JONES‘. . . has more importance than the intrinsic value of the informa-tion it carries. Its very existence illustrates in a lively fashion theevolution from qualitative to quantitative science that is rapidlytaking place in the still young but vigorously developing subject ofbiochemistry.’ NEW SCIENTIST Text-figures 63s netExperimental Techniques in Low-Temperature PhysicsGUY KENDALL WHITE‘. .. the first of its kind in being wholly given over to the tech-niques of low temperature work, and it will meet a long-felt need.Research students just starting such work and those peoplewishing to extend investigations over a wider temperature rangewill find this publication timely and of great help. . . . Theestablished worker in the field will also find much of value in thisbook.’ BRITISH JOURNAL OF APPLIED PHYSICS (Monographs on thePhysics and Chemistry of Materials). Plates and text-figures 45s netDetermination of Molecular StructureP. J. WHEATLEYThis book discusses the main physicochemical methods used todetermine molecular structure. The scope and limitations of eachpethod are emphasized and examples drawn from original papers. . . . will undoubtedly be of great value to first-year universitystudents and should stimulate them to read more advanced textsto which many references are given.’ JOURNAL OF THE ROYALINSTITUTE OF CHEMISTRY Text-figures 35s netOXFORD UNIVERSITY PRESS-xiiApplied Pe tr o le urn Reservoir EngineeringB. C. CRAFT & M. F. HAWKINS, JR.The growth of the petroleum industry demands improvedscientific methods for the analysis and prediction of oilreservoir and well performance. This book is a significantcontribution to this subject, which now constitutes a well-defined, highly technical branch of petroleum engineering.Med. 8vo. 437 pages. Illustrated. 62s. 6d.Fundamentals of Chemical EngineeringOperationsM. G. LARIANA textbook which covers the most important elements of awide subject concisely and on a level suitable for under-graduate instruction.Med. 8vo. 644 pages. Illustrated. 62s. 6d.Soil Chemical AnalysisM. L. JACKSONThis book gives the most frequently used soil chemicalanalysis procedures, useful in instruction and research in soilchemistry, soil fertility and soil genesis. Because plantgrowth is essentially related to these fields, procedures aregiven for plant inorganic constituents.Med. 8vo. 498 pages. Illustrated. 57s. 6d.Electrochemical Processes in ChemicalIndustriesA. REGNERThe theoretical part of this book deals with basic laws; goeson to discuss electrolytic conductance and various types ofgalvanic cells and concludes with a section on electrolysisand polarization. The second part deals with industrialapplications.Ex. Cr. 8vo. 464pages. 149 figures. 1957. 30s.Chemical Engineering Operations: An Intro-duction to the Study of Chemical PlantF. RUMFORDSecond edition. Demy 8vo. 387 pages. Illustrated. 1957.32s. 68.Chemical Engineering MaterialsF. RUMFORDA major change in this second edition is the complete re-writing of the chapter on plastics as a material for use inSecond edition. Demy 8vo. 400 pages. Illustrated. 32s. 6d.' chemical plant.CONSTABLE 8~ CO. LTD10 ORANGE STREET, LONDON, W.C.2xi

 

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