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A Different Proof of the Maxwell-Boltzmann Distribution

 

作者: P. A. Mello,   T. A. Brody,  

 

期刊: American Journal of Physics  (AIP Available online 1972)
卷期: Volume 40, issue 9  

页码: 1239-1345

 

ISSN:0002-9505

 

年代: 1972

 

DOI:10.1119/1.1986808

 

出版商: American Association of Physics Teachers

 

数据来源: AIP

 

摘要:

The Maxwell-Boltzmann Distribution (MBD) for a classical ideal gas is obtained as the mean over phase space of the number of momentum components less than some value p, without making any assumptions beyond those implicit in the microcanonical ensemble. The variance of the fluctuations of actual distributions of the momentum around the average given by the MBD is shown to go to zero asN−1,whereNis the number of particles. This proof of the MBD has the advantage over the usual type of proof in that it does not employ a subdivision of phase space into cells, a trick which gives rise to certain difficulties discussed in the introduction. Moreover, it is more complete in that the problem of the fluctuations is treated at an elementary level.

 

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