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N.M.R. studies of electrolytes in binary solvent mixtures I. 10:1 aqueous mixtures of a...
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N.M.R. studies of electrolytes in binary solvent mixtures I. 10:1 aqueous mixtures of acetone, N,N-dimethylformamide, dimethylsulphoxide, dioxane, ethanol, and N-methylformamide
作者:
Anthony Fratiello,
DonPaul Miller,
期刊:
Molecular Physics
(Taylor Available online 1966)
卷期:
Volume 11,
issue 1
页码: 37-47
ISSN:0026-8976
年代: 1966
DOI:10.1080/00268976600100831
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
A N.M.R. study of diamagnetic salts and CoCl2in pure water and in 10 : 1 mole ratio aqueous mixtures of acetone, N,N-dimethylformamide, dimethylsulphoxide, dioxane, ethanol, methanol and N-methylformamide, has been carried out. Water chemical shift displacements indicate that this component extensively solvates most cations. These displacements are correlated with ion charge, entropy, size, and with the water concentration. Evidence for solvation by the organic component was provided by the water results, AlCl3solution studies, and paramagnetic studies. In the AlCl3solutions, in the DMF, DMSO, and NMF-H2O solvent mixtures, separate N.M.R. signals were observed for bulk and complexed organic solvent.
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