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Excess Molar Volumes and Viscosities for 1,1,1-Trichloroethane with Alcohols at 298.15 K

 

作者: SusanaB. De Katz,   GracielaC. Pedrosa,   Miguel Katz,  

 

期刊: Physics and Chemistry of Liquids  （Taylor Available online 1991）
卷期: Volume 23, issue 1  

页码: 15-26

 

ISSN:0031-9104

 

年代: 1991

 

DOI:10.1080/00319109108030629

 

出版商: Taylor & Francis Group

 

关键词: Excess molar volumes;excess viscosities;excess activation energies;1,1,1-trichloroethane + (1-propanol,1-butanol,2-butanol and 3-methyl-1-butanol).

 

数据来源: Taylor

 

摘要:

Excess molar volumes (VE), excess viscosities (ηE) and excess energies of activation for viscous flow (δG*E) have been obtained for the 1,1,1-trichloroethane + alcohols systems at 298.15 K, over the whole concentration range. The Prigogine-Flory-Patterson model of solution thermodynamics has been used to predict the excess molar volumes. McAllister, Teja and Rice and Schrodt and Akel models have been used to predict viscosity coefficients and these were compared with experimental data, for the mixtures.

 

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