Rapid and Sensitive Screening Method for the Determination of Carbaryl and Propoxur Using p-Nitroaniline
作者:
J. Raju,
P. Shivhare,
V.K. Gupta,
期刊:
International Journal of Environmental Analytical Chemistry
(Taylor Available online 1992)
卷期:
Volume 49,
issue 3
页码: 111-115
ISSN:0306-7319
年代: 1992
DOI:10.1080/03067319208027562
出版商: Taylor & Francis Group
关键词: Carbaryl;propoxur;water;grain;spectrophotometry
数据来源: Taylor
摘要:
A rapid screening method for the determination of carbaryl and propoxur using p-nitroaniline is described. Carbaryl and propoxur are determined spectrophotometrically: carbaryl forms a stable blue coloured species with diazotized p-nitroaniline in a fairly alkaline medium while propoxur forms a purple coloured species with the same reagent under similar conditions. The blue and purple coloured species are extracted into 3-methyl-1-butanol showing absorbance maxima at 605 and 540 nm, respectively. The relationship between absorbance and concentration is linear in the range of 0.12 - 0.96 ppm and 0.19–1.5 ppm, respectively for carbaryl and propoxur. The method can successfully be applied for the determination of carbaryl and propoxur to levels as low as 0.04 and 0.06 and 0.12 and 0.19 ppm in water and grain samples, respectively.
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