New Precision Thermometric Titration Calorimeter
作者:
J. J. Christensen,
R. M. Izatt,
L. D. Hansen,
期刊:
Review of Scientific Instruments
(AIP Available online 1965)
卷期:
Volume 36,
issue 6
页码: 779-783
ISSN:0034-6748
年代: 1965
DOI:10.1063/1.1719702
出版商: AIP
数据来源: AIP
摘要:
A new solution calorimeter is described which combines the thermometric titration techniques with the precision and accuracy of conventional solution calorimetry. The calorimeter through use of a unique design has a low heat leakage,k= 1.1×10−3min−1, and a short equilibration period, 1–3 sec. Measurements of quantities of heat as small as 4 calories with an accuracy of 0.1% are possible. The heat of ionization of water at zero ionic strength has been determined to be 13.34±0.02 kcal/mole which is in excellent agreement with the value of 13.34±0.01 kcal/mole determined by conventional solution calorimetry. The large amount of information obtained from a single run makes this type of calorimeter a valuable addition to the field of solution calorimetry.
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