Variable-frequency electron paramagnetic resonance
作者:
Richard Bramley,
期刊:
International Reviews in Physical Chemistry
(Taylor Available online 1986)
卷期:
Volume 5,
issue 2-3
页码: 211-217
ISSN:0144-235X
年代: 1986
DOI:10.1080/01442358609353385
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The principal sources of errors in the determination of parameters of the spin hamiltonian by conventional electron paramagnetic resonance (E.P.R.) experiments are identified. It is possible to circumvent these errors by performing an E.P.R. experiment in zero magnetic field, scanning the frequency. The benefits of zero-field (electron paramagnetic) resonance (Z.F.R.) and of combining E.P.R. and Z.F.R. techniques in a variable-frequency, variable-field experiment are listed and discussed. Such an approach offers a challenge to theorists to calculate the higher-order parameters which can now be obtained with high accuracy. Experimental advantages are also discussed.
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