Photochromic Sol-Gel Films Containing Dithienylethene and Azobenzene Derivatives: From the Design of Optical Components to the Optical Data Storage
作者:
F. Chaput,
J. Biteau,
K. Lahlil,
J.P. Boilot,
B. Darracq,
Y. Levy,
J. Peretti,
V.I. Safarov,
G. Parent,
A. Fernandez-Acebes,
J-M. Lehn,
期刊:
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
(Taylor Available online 2000)
卷期:
Volume 344,
issue 1
页码: 77-82
ISSN:1058-725X
年代: 2000
DOI:10.1080/10587250008023817
出版商: Taylor & Francis Group
关键词: Dithienylethene;Azobenzene;hybrid material;sol-gel;data storage;optical components
数据来源: Taylor
摘要:
This work is devoted to photoresponsive hybrid organic-inorganic materials prepared by the sol-gel method, using dithienylethene or azobenzene as photosensitive chromophores. These photochromic units were covalently attached to the silica backbone as part of the main-chain and as a side group respectively. The electrocyclization of dithienylethene or the isomerization of azobenzene under irradiation cause local modifications of the optical properties of the host sol-gel polymers We took advantage of either high refractive index changes (>10−2) or material deformation of the sol-gel films to design optical components and to store information.
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