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Photochromic Sol-Gel Films Containing Dithienylethene and Azobenzene Derivatives: From the Design of Optical Components to the Optical Data Storage

 

作者: F. Chaput,   J. Biteau,   K. Lahlil,   J.P. Boilot,   B. Darracq,   Y. Levy,   J. Peretti,   V.I. Safarov,   G. Parent,   A. Fernandez-Acebes,   J-M. Lehn,  

 

期刊: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals  (Taylor Available online 2000)
卷期: Volume 344, issue 1  

页码: 77-82

 

ISSN:1058-725X

 

年代: 2000

 

DOI:10.1080/10587250008023817

 

出版商: Taylor & Francis Group

 

关键词: Dithienylethene;Azobenzene;hybrid material;sol-gel;data storage;optical components

 

数据来源: Taylor

 

摘要:

This work is devoted to photoresponsive hybrid organic-inorganic materials prepared by the sol-gel method, using dithienylethene or azobenzene as photosensitive chromophores. These photochromic units were covalently attached to the silica backbone as part of the main-chain and as a side group respectively. The electrocyclization of dithienylethene or the isomerization of azobenzene under irradiation cause local modifications of the optical properties of the host sol-gel polymers We took advantage of either high refractive index changes (>10−2) or material deformation of the sol-gel films to design optical components and to store information.

 

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