Physico-Chemical Studies of Solvent-Solvent and Ion-Solvent Interactions in Solutions of Lithium Nitrate in Dimethyl-Sulphoxide +Ethanol Mixtures
作者:
A. Ali,
A.K. Nain,
期刊:
Physics and Chemistry of Liquids
(Taylor Available online 1997)
卷期:
Volume 34,
issue 1
页码: 25-40
ISSN:0031-9104
年代: 1997
DOI:10.1080/00319109708035911
出版商: Taylor & Francis Group
关键词: Physico-chemical studies;solvent-solvent;ion-solvent interactions
数据来源: Taylor
摘要:
Densities (ρ), viscosities (η), and ultrasonic velocities (u) through solutions of lithium nitrate in dimethylsulphoxide (DMSO) + ethanol mixtures have been measured as a function of electrolyte concentration and temperature. The suitability of various polynomial equations in reproducing the experimental values of ρ, η, anduwas checked for the present system. The adiabatic compressibility (β), intermolecular free length (Lf), relative association (RA), specific acoustic impedance (Z), molar sound velocity (Rm), enthalpy (ΔH*) and entropy (ΔS*) of activation of viscous flow have been computed. The results are explained in terms of solvent-solvent and ion-solvent interactions.
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