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Physico-Chemical Studies of Solvent-Solvent and Ion-Solvent Interactions in Solutions of Lithium Nitrate in Dimethyl-Sulphoxide +Ethanol Mixtures

 

作者: A. Ali,   A.K. Nain,  

 

期刊: Physics and Chemistry of Liquids  (Taylor Available online 1997)
卷期: Volume 34, issue 1  

页码: 25-40

 

ISSN:0031-9104

 

年代: 1997

 

DOI:10.1080/00319109708035911

 

出版商: Taylor & Francis Group

 

关键词: Physico-chemical studies;solvent-solvent;ion-solvent interactions

 

数据来源: Taylor

 

摘要:

Densities (ρ), viscosities (η), and ultrasonic velocities (u) through solutions of lithium nitrate in dimethylsulphoxide (DMSO) + ethanol mixtures have been measured as a function of electrolyte concentration and temperature. The suitability of various polynomial equations in reproducing the experimental values of ρ, η, anduwas checked for the present system. The adiabatic compressibility (β), intermolecular free length (Lf), relative association (RA), specific acoustic impedance (Z), molar sound velocity (Rm), enthalpy (ΔH*) and entropy (ΔS*) of activation of viscous flow have been computed. The results are explained in terms of solvent-solvent and ion-solvent interactions.

 

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