Partial Coordination Numbers and Flory-Huggins Equation of Binary Hard Sphere Systems with Unequal Hard Sphere Diameters
作者:
H. Ruppersbergfb,
期刊:
Physics and Chemistry of Liquids
(Taylor Available online 1988)
卷期:
Volume 18,
issue 1
页码: 1-9
ISSN:0031-9104
年代: 1988
DOI:10.1080/00319108808078572
出版商: Taylor & Francis Group
关键词: Partial coordination numbers;Flory-Huggins equation;interchange energy.
数据来源: Taylor
摘要:
Partial radial distribution functions of binary hard sphere systems with strong size difference between the constituting atoms are calculated starting from the Percus-Yevick equation. Partial coordination numbers of nearest neighbours are defined. Empirical relations are found which give partial coordination numbers of an accuracy better than 1 % as a function of packing fraction (0.2 ±n ±0.5), size difference([sgrave]2/[sgrave]1±1.44) and composition. Introduction of pairwise interactions between nearest neighbours yields for the enthalpy of mixing approximately the same composition dependence as given by the Flory-Huggins equation, and explains why the numerical value of the “interchange energy” depends on the choice of indexing the constituents.
点击下载:
PDF (408KB)
返 回