Proton Magnetic Resonance Studies of Al(III) and Ga(III) Hydration Numbers in Aqueous Solution
作者:
J.W. Akitt,
N.N. Greenwood,
B. Kandelwahl,
期刊:
Spectroscopy Letters
(Taylor Available online 1971)
卷期:
Volume 4,
issue 5
页码: 139-140
ISSN:0038-7010
年代: 1971
DOI:10.1080/00387017108064628
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Schweitzer and Stephens have recently suggested that the hydration numbers of Al3+and Ga3+and Ga3+in aqueous solutions containing a considerable excess of chloride ion are probably less than six. Hydration numbers as low as 4.64 (in 1.44 M AlCl3+ 2.15 M CaCl2) or 4.61 (in 0.645 M GaCl3+ 3.32 M CaCl2) were obtained.1That Ga3+forms chloro-complexes under these conditions is well known though interaction between Al3+and chloride is considered unlikely in aqueous solution.2–4
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