Fluoreszenz‐Detektion für die Multielement‐Bestimmung von Kationen nach HPLC‐Trennung
作者:
Th. Vortmüller,
G. Wünsch,
期刊:
Journal für Praktische Chemie/Chemiker‐Zeitung
(WILEY Available online 1994)
卷期:
Volume 336,
issue 1
页码: 11-15
ISSN:0941-1216
年代: 1994
DOI:10.1002/prac.19943360104
出版商: WILEY‐VCH Verlag GmbH
数据来源: WILEY
摘要:
Fluorescence Detection System for the Multielement Determination of Cations after Separation by HPLCFluorescence determination of cations after HPLC separation requires an unselective detection principle to achieve multielement capability. Following the principle of the photometric Zn‐EDTA‐PAR‐system, 2, 2′‐pyridylbenzimidazole (PBI) is used as a fluorescent indicator. Cations are separated on a Nucleosil 5SA column using tartaric acid as eluent. Zn is replaced by the eluent traces in a post column reactor and determined as the fluorescent Zn‐PBI‐chelate. Detection limits for Mn, Mg, Ca, Cu, Cd are 7–92 ng in 20 μL
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