Flow‐Induced Birefringence of Concentrated Polyisoprene Solutions
作者:
Dale S. Pearson,
Andrea D. Kiss,
Lewis J. Fetters,
Masao Doi,
期刊:
Journal of Rheology
(AIP Available online 1989)
卷期:
Volume 33,
issue 3
页码: 517-535
ISSN:0148-6055
年代: 1989
DOI:10.1122/1.550026
出版商: The Society of Rheology
数据来源: AIP
摘要:
Experiments measuring the birefringence following the inception of a steady shearing flow were conducted on a series of concentrated polyisoprene solutions. The steady‐state shear stress was also measured in a mechanical rheometer. The data obtained from the two experiments confirmed that the birefringence and stress were linearly related (stress‐optical law) over a range of shear rates that extended far into the non‐Newtonian region. Interesting nonlinear effects were also observed during the transient response at high shear rates. Both the shear stress and the first normal stress pass through maximums before reaching their steady‐state values. A maximum in the normal stress is not predicted by the original Doi‐Edwards model but a modification of their theory which includes chain stretching is in qualitative agreement with our results.
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