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Influence of tensile strain on the corrosion of preoxidized MA 956 in an S-O-C-bearing atmosphere

 

作者: GuttmannV.,   MediavillaA.,   RuanoO.,  

 

期刊: Materials at High Temperatures  (Taylor Available online 1993)
卷期: Volume 11, issue 1-4  

页码: 42-50

 

ISSN:0960-3409

 

年代: 1993

 

DOI:10.1080/09603409.1993.11689438

 

出版商: Taylor&Francis

 

关键词: tensile strain;corrosion;alloy preoxidation

 

数据来源: Taylor

 

摘要:

This paper deals with an investigation into the protective limit of an oxide scale preformed on the ODS alloy MA 956. The experiments were carried out under creep conditions for different strains and strain rates at 600°C up to 8000 h exposure. The possible consequences of scale rupture on the quality of protection have been analysed by exposing the alloy in an S-O-C-bearing gas of low oxygen and medium sulfur potentials which was intended to simulate a coal-gasification atmosphere. The results have shown that MA 956 forms an adherent A12O3scale about 1.5μm thick after preannealing for 2h at 1100°C. This scale exhibited full protection even after long-term exposure. Scale cracking was first observed in the range 0.5−0.6% total strain. No influence on the critical strain value due to strain rate could be observed in the range 10−10−2×10−7s−1. Cracking could be identified by surface examination due to the external corrosion taking place along the cracks. The onset of corrosion resulting from scale cracking was characterized by the formation of Cr-rich (Cr, Fe)-sulfides on the outside of the scale. With progressing time, external Fe-rich (Fe, Cr)-sulfides were also observed, and internal oxidation and sulfidation occurred in parallel. With larger strains, e.g. more than about 1%, indications of scale spallation were found.

 

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