A Flow Reactor Study of the Oxidation of Iso-butylene and an Iso-butyleneln-octane Mixture
作者:
K. Brezinsky,
F. L. Dryer,
期刊:
Combustion Science and Technology
(Taylor Available online 1986)
卷期:
Volume 45,
issue 5-6
页码: 225-232
ISSN:0010-2202
年代: 1986
DOI:10.1080/00102208608923853
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
An examination has been conducted of the oxidation of iso-butylene and an iso-butylene/n-octane mixture at 1080 K and one atmosphere. It was found that the addition of iso-butylene to n-octane results in a delay in the formation of CO and CO2even ifenough additional O2is added to maintain a n overall equivalence ratio of one. Analysis of the oxidation of iso-butylene alone suggests that the inhibiting effect of iso-butylene addition results from a reduction in radical concentrations due to the abstraction reactions of the radicals with the iso-butylene to yield unreactive methyl radicaland allene.
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