首页   按字顺浏览 期刊浏览 卷期浏览 Physico‐Chemical Aspects of Chemically Active Ultrasonic Cavitation in Aqueous Solutions
Physico‐Chemical Aspects of Chemically Active Ultrasonic Cavitation in Aqueous Solutions

 

作者: Olle Lindström,  

 

期刊: The Journal of the Acoustical Society of America  (AIP Available online 1955)
卷期: Volume 27, issue 4  

页码: 654-671

 

ISSN:0001-4966

 

年代: 1955

 

DOI:10.1121/1.1907987

 

出版商: Acoustical Society of America

 

数据来源: AIP

 

摘要:

Quantitative measurements have been performed on some fundamental phenomena caused by ultrasonic cavitation, i.e., the synthesis of hydrogen peroxide, the oxidation of potassium iodide, the decomposition of carbon tetrachloride, the degassing action, and the evolution of heat in connection with the cavitation process. The experiments were made under controlled and defined acoustic conditions (standing waves, progressive waves, and non‐resonance) and the influences by various important factors (acoustic intensity, gas content) have been evaluated.Tentative theories of the cavitation process and allied phenomena are evaluated on the basis of the experimental results. Cavitation chemistry is found to be similar to gamma radiation chemistry (pH‐dependence of the yield of hydrogen peroxide, oxidation of solutes, necessity of oxygen). Cavitation is assumed to be preceded by a homogeneous nucleation process in which a germ or gas nucleus is being formed by rupture of the liquid around this germ. Ionization of some of the gas molecules entrained in the cavity will take place in order to establish the electric charge of the surface of the cavity. Two hydrogen peroxide molecules are formed for every ionized oxygen molecule. It is supposed that in the case of oxygen a cluster is formed by the combination of two water molecules and a positive oxygen ion. This cluster yields on decomposition at the neutralization two hydroxyl radicals and one excited hydrogen perioxide molecule.The rate of cavitation seems to be independent of (1) the gas concentration (above the threshold concentration), (2) the pressure amplitude (above the threshold amplitude and within the region of cavitation), and (3) the nature of the dissolved gas (provided the gas may initiate homogeneous cavitation at all). These features indicate that properties of the liquid are rate determining when the various threshold requirements are fulfilled. A tentative picture of the nucleation process is presented, which seems to satisfy these conditions.The degassing action in an ultrasonic field proceeds to half saturation practically independent of the intensity.A method for cavitation dosimetry is described.

 

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