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Five-coordinate dicarbonyl complexes of rhodium(I): [RhX(CO)2(PPh3)2] (X = Cl, Br, I)

 

作者: Alan R. Sanger,  

 

期刊: Canadian Journal of Chemistry  （NRC Available online 1985）
卷期: Volume 63, issue 3  

页码: 571-575

 

ISSN:0008-4042

 

年代: 1985

 

DOI:10.1139/v85-093

 

出版商: NRC Research Press

 

数据来源: NRC

 

摘要:

The complexestrans-[RhX(CO)PPh3)2] (1, X = Cl, Br, I) react with CO to form [RhX(CO)2(PPh3)2] (2), and not to formcis-[RhX(CO)(PPh3)2]. Complexes2contain equivalent axial carbonyl ligands. It is proposed that a series of dicarbonyl complexes, including2, is formed during decarbonylation reactions catalyzed by1.

 

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