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Partial Molar Volume Anomaly in Supercritical Mixtures and the Free Radical Polymerization of Ethylene

 

作者: Paul Ehrlich,  

 

期刊: Journal of Macromolecular Science: Part A - Chemistry  （Taylor Available online 1971）
卷期: Volume 5, issue 8  

页码: 1259-1263

 

ISSN:0022-233X

 

年代: 1971

 

DOI:10.1080/00222337108061105

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The anomalous properties of the supercritical region require that, when the pressure-coefficient of the rate constant is expressed according to transition-state theory, the meaning of the term “volume of activation” be analyzed with care. Applications to the polymerization of ethylene are shown.

 

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