Secondary Structure of Rabbit Cd5Zn2MT-II, Zn7MT-II and Pt7MT-II By Fourier Transform Infrared Spectroscopy
作者:
Pei Huang,
Ben-gang Xing,
Jiang-lin Fang,
Wen-xia Tang,
期刊:
Spectroscopy Letters
(Taylor Available online 1998)
卷期:
Volume 31,
issue 7
页码: 1599-1608
ISSN:0038-7010
年代: 1998
DOI:10.1080/00387019808001663
出版商: Taylor & Francis Group
关键词: Secondary structure analysis;NMR analysis;FTIR spectroscopy and Metallotioneins (MTs)
数据来源: Taylor
摘要:
The secondary structures of Cd5Zn2MT-II and Zn7MT-II from rabbit liver and their derivative Pt7MT-II in solid state were investigated by Fourier transform is spectroscopy. The Cd5Zn2MT-II contains about 30% turns and half turns, 17% 310-helix, 4% unordered and 9% β-extended chain, which is similar to the content determined by the nmr analysis and is similar to the structures of the Pt7MT-II and Zn7MT-II. The results indicate that there is no evident conformation changes of MTs' secondary structure when the tetrahedral Zn and Cd ions of native MTs are replaced by square-planar Pt ion.
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