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Rotational Plastometry Applied to Molten Polyethylene

 

作者: F. D. Dexter,  

 

期刊: Journal of Applied Physics  (AIP Available online 1954)
卷期: Volume 25, issue 9  

页码: 1124-1129

 

ISSN:0021-8979

 

年代: 1954

 

DOI:10.1063/1.1721826

 

出版商: AIP

 

数据来源: AIP

 

摘要:

A concentric cylinder rotational plastometer which automatically plots the shear strainvstime curve for each of a number of shear stresses is described. The flow behavior of molten polyethylene resins, measured with this instrument from 130°C to 210°C, is discussed. It is shown that, at each shear stress, the shear strainvstime curve for these resins is describable in terms of a viscosity, an elastic shear strain and a retardation time. As the shear stress is raised both the viscosity and retardation time decrease, while the elastic shear strain increases. The shear stress dependency of the viscosity and elastic shear strain are shown to be related and in a manner which suggests that the viscosity change is the result of an entropy effect.

 

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