Thermodynamic Properties of Aqueous Sodium Chloride Solutions
作者:
Kenneth S. Pitzer,
J. Christopher Peiper,
R. H. Busey,
期刊:
Journal of Physical & Chemical Reference Data
(AIP Available online 1984)
卷期:
Volume 13,
issue 1
页码: 1-102
ISSN:0047-2689
年代: 1984
DOI:10.1063/1.555709
出版商: AIP
数据来源: AIP
摘要:
Experimental measurements of the osmotic and activity coefficients, the enthalpy, and the heat capacity were used to derive a semiempirical equation for the thermodynamic properties of NaCl(aq) at constant pressure. This equation may be combined with results contained in the previous paper on the volumetric properties to yield a complete equation of state valid in the region 273 K≤T≤573 K, saturation pressure ≤P≤1 kbar, 0≤m≤6.0 mol kg−1. It is shown that this equation may be extrapolated to higher solute molalities at lower pressures. An estimation of uncertainties in various quantities is given. Tables of values for various thermodynamic properties are presented in the appendix.
点击下载:
PDF
(5748KB)
返 回