首页   按字顺浏览 期刊浏览 卷期浏览 Thermodynamic Properties of Aqueous Sodium Chloride Solutions
Thermodynamic Properties of Aqueous Sodium Chloride Solutions

 

作者: Kenneth S. Pitzer,   J. Christopher Peiper,   R. H. Busey,  

 

期刊: Journal of Physical & Chemical Reference Data  (AIP Available online 1984)
卷期: Volume 13, issue 1  

页码: 1-102

 

ISSN:0047-2689

 

年代: 1984

 

DOI:10.1063/1.555709

 

出版商: AIP

 

数据来源: AIP

 

摘要:

Experimental measurements of the osmotic and activity coefficients, the enthalpy, and the heat capacity were used to derive a semiempirical equation for the thermodynamic properties of NaCl(aq) at constant pressure. This equation may be combined with results contained in the previous paper on the volumetric properties to yield a complete equation of state valid in the region 273 K≤T≤573 K, saturation pressure ≤P≤1 kbar, 0≤m≤6.0 mol kg−1. It is shown that this equation may be extrapolated to higher solute molalities at lower pressures. An estimation of uncertainties in various quantities is given. Tables of values for various thermodynamic properties are presented in the appendix.

 

点击下载:  PDF (5748KB)



返 回