Third Harmonic Generation in Conjugated Polymers: Exciton Effect and Influence of Disorder
作者:
S. Abe,
M. Schreiber,
W.P. Su,
J. Yu,
期刊:
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
(Taylor Available online 1992)
卷期:
Volume 217,
issue 1
页码: 1-6
ISSN:1058-725X
年代: 1992
DOI:10.1080/10587259208046867
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Nonlinear optical susceptibilities of conjugated polymers are studied in the Su-Schrieffer-Heeger model supplemented by long-range Coulomb interactions, taking account of the formation of excitons and the influence of disorder. In the calculated third-harmonic generation spectrum, on the high energy side of the main peak (due to the lowest singlet exciton) a second peak (due to the three-photon resonance to the electron-hole continuum) is found that is strong enough to remain significant even in the presence of disorder. The results are in good agreement with experiments in polydiacetylene and polythiophene.
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