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Third Harmonic Generation in Conjugated Polymers: Exciton Effect and Influence of Disorder

 

作者: S. Abe,   M. Schreiber,   W.P. Su,   J. Yu,  

 

期刊: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals  (Taylor Available online 1992)
卷期: Volume 217, issue 1  

页码: 1-6

 

ISSN:1058-725X

 

年代: 1992

 

DOI:10.1080/10587259208046867

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Nonlinear optical susceptibilities of conjugated polymers are studied in the Su-Schrieffer-Heeger model supplemented by long-range Coulomb interactions, taking account of the formation of excitons and the influence of disorder. In the calculated third-harmonic generation spectrum, on the high energy side of the main peak (due to the lowest singlet exciton) a second peak (due to the three-photon resonance to the electron-hole continuum) is found that is strong enough to remain significant even in the presence of disorder. The results are in good agreement with experiments in polydiacetylene and polythiophene.

 

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