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Formation of Azobenzenes and Azoxybenzenes from the Aqueous Reactions of Anilines and Ozone

 

作者: WayneF. Chan,   RichardA. Larson,  

 

期刊: Ozone: Science & Engineering  （Taylor Available online 1995）
卷期: Volume 17, issue 6  

页码: 619-625

 

ISSN:0191-9512

 

年代: 1995

 

DOI:10.1080/01919512.1995.10555773

 

出版商: Taylor & Francis Group

 

关键词: Ozone;Aniline;Azobenzenes;Azoxybenzenes;Electron-Withdrawing Group Effects;Electron-Donating Group Effects

 

数据来源: Taylor

 

摘要:

Azobenzenes and azoxybenzenes are two of the products identified from the aqueous reaction of anilines with ozone. Aniline concentration and functional groups on the benzene ring of aniline affected the amount of azobenzenes and azoxybenzenes formed; (1) decreasing the aniline concentration significantly increased azobenzene formation, and (2) electron-withdrawing groups increased the formation of its related azobenzene and azoxybenzene, whereas electron-donating groups had the opposite effect.

 

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