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Heat capacity and other thermodynamic properties of linear macromolecules. II. Polyethylene

 

作者: Umesh Gaur,   Bernhard Wunderlich,  

 

期刊: Journal of Physical & Chemical Reference Data  (AIP Available online 1981)
卷期: Volume 10, issue 1  

页码: 119-152

 

ISSN:0047-2689

 

年代: 1981

 

DOI:10.1063/1.555636

 

出版商: AIP

 

数据来源: AIP

 

摘要:

The heat capacity of polyethylene from 0 K to 600 K is reviewed using measurements on 46 samples reported in the literature. The crystallinity dependence is evaluated critically and a set of recommended data for completely crystalline and amorphous polyethylene is derived. Entropy, enthalpy, and Gibbs energy functions are calculated. Polyethylene can serve as a standard material for the thermodynamic functions of a simple linear macromolecule. This paper is the second in a series which will ultimately cover all heat capacity measurements on linear macromolecules.

 

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