Stacked metallomacrocycles [MacM(L)]ncan be obtained by the so-called “shish kebab” approach1in which transition metallomacrocycles (MacM) are linked together by bidentate bridging ligands Q. Such bridged Macrocyclic metal compounds [MacM(L)]nwith transition metals e.g. Fe, Ru, Os, Co, Rh in various oxidation states have been synthesized by us.1Mostly as macrocycles (Mac), not only phthalocyanine (Pc), tetrabenzoporphyrine (TBP), but also macrocycles containing more extended p-systems like 1,2- or 2,3-naphthalocyanine (1,2-, 2,3-Nc) or phenanthrenocyanine (Phc) are used.1,2,3The bridging ligands (L) are bifunctional organic donor molecules, e.g. pyrazine (pyz),s-tetrazine (tz),p-diisocyanobenzene (dib), 1,4-diazabicyclo[2.2.2]octane (dabco) for metals in the oxidation state +2, or e.g. cyanide (CN−), thiocyanate (SCN−) or aide (N3−) for transition metals in the oxidation state +3.1aIn general, these complexes [MacM(L)]nare insoluble in organic solvents, however, soluble oligomers [R4PcM(L)]ncan be prepared using metallomacrocycles R4PcM, R =t-bu, et, M = Fe, Ru, which are substituted in the peripheric positions.4