Raman spectroscopy under pressure using a diamond pressure vessel
作者:
P. T. T. Wong,
E. Whalley,
期刊:
Review of Scientific Instruments
(AIP Available online 1974)
卷期:
Volume 45,
issue 7
页码: 904-906
ISSN:0034-6748
年代: 1974
DOI:10.1063/1.1686764
出版商: AIP
数据来源: AIP
摘要:
A transparent pressure vessel made of diamond has been used to study Raman spectra under pressure. It has the advantage that the relative displacement of the pressurizing pistons can be used to determine directly the change of density of the sample and to determine directly the Gru¨neisen parameter, and it can easily be heated or cooled over a wide temperature range by a gas stream. The relative displacement of the piston can also be used to identify the phase being examined, which is particularly valuable when a substance with a complicated phase diagram is being studied. The Raman spectra of the translational vibrations of ammonium fluoride II and of the rotational vibrations of anthracene have been studied using the cell.
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