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Time‐temperature superposition in two‐phase polyblends

 

作者: D. Kaplan,   N. W. Tschoegl,  

 

期刊: Polymer Engineering&Science  (WILEY Available online 1974)
卷期: Volume 14, issue 1  

页码: 43-49

 

ISSN:0032-3888

 

年代: 1974

 

DOI:10.1002/pen.760140108

 

出版商: Society of Plastics Engineers, Inc.

 

数据来源: WILEY

 

摘要:

AbstractThe temperature dependence of the mechanical properties of a 50/50 blend of PVAC and lightly crosslinked PMMA has been examined using the data of Kawaiet al.The shift distances, logaT, were generated by bringing the experimental data into coincidence on master curves calculated from a Takayanagi model whose parameters were varied in different regions of temperature. This method allows one to construct a master curve for a thermorheologically complex two‐phase material if the model and the mechanical properties of the constituent phases and their temperature dependence is known. The shift distances then provide insight into the intricate relations between the time and temperature dependence of the mechanical properties of the composit

 

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