Studies on Thermodynamic Properties of Polyvalent Electrolytes from E. M. F. Measurements. II. The Silver‐Silver Molybdate Electrode
作者:
Kuan Pa,
期刊:
Journal of the Chinese Chemical Society
(WILEY Available online 1954)
卷期:
Volume 1,
issue 1
页码: 16-25
ISSN:0009-4536
年代: 1954
DOI:10.1002/jccs.195400002
出版商: WILEY‐VCH Verlag
数据来源: WILEY
摘要:
Abstract(1)The solubility‐product of silver molybdate was determined by the e.m.f. measurements of the cell,by extrapolation method in the temperature range of 20° to 40°C.(2)The standard potential of the Ag;Ag2MoO4(s);MoO4−electrode, and the molal heat and molal free energy for the solution of silver molybdate are expressed as a function of temperature over the temperature range of 20° to 40°C as follows:(3)The molal heat, free energy and entropy change for the formation of silver molybdate from its elements at 25°C are eva
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