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Studies on Thermodynamic Properties of Polyvalent Electrolytes from E. M. F. Measurements. II. The Silver‐Silver Molybdate Electrode

 

作者: Kuan Pa,  

 

期刊: Journal of the Chinese Chemical Society  (WILEY Available online 1954)
卷期: Volume 1, issue 1  

页码: 16-25

 

ISSN:0009-4536

 

年代: 1954

 

DOI:10.1002/jccs.195400002

 

出版商: WILEY‐VCH Verlag

 

数据来源: WILEY

 

摘要:

Abstract(1)The solubility‐product of silver molybdate was determined by the e.m.f. measurements of the cell,by extrapolation method in the temperature range of 20° to 40°C.(2)The standard potential of the Ag;Ag2MoO4(s);MoO4−electrode, and the molal heat and molal free energy for the solution of silver molybdate are expressed as a function of temperature over the temperature range of 20° to 40°C as follows:(3)The molal heat, free energy and entropy change for the formation of silver molybdate from its elements at 25°C are eva

 

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