Measurements of the Mechanical Properties of Polymer Solutions by Electromagnetic Transducers
作者:
Thor L. Smith,
John D. Ferry,
Frederic W. Schremp,
期刊:
Journal of Applied Physics
(AIP Available online 1949)
卷期:
Volume 20,
issue 2
页码: 144-153
ISSN:0021-8979
年代: 1949
DOI:10.1063/1.1698326
出版商: AIP
数据来源: AIP
摘要:
A concentrated polymer solution is sheared by a rod oscillating axially with a very small amplitude in a closed tube. The rod is driven by a coil in a magnetic field; from electrical measurements on the coil, the mechanical resistance and reactance of the system are calculated by transducer relationships. Equations are given for obtaining the dynamic viscosity, &eegr;′, and rigidity,G′, of the solution. In the case of some polymer solutions, the audiofrequency range covered by the present apparatus falls in the dispersion zone where &eegr;′ andG′change rapidly with frequency. In other cases the frequency range covered appears to be at the upper end of the dispersion zone; &eegr;′ is far smaller than the viscosity in steady flow, andG′changes very little with frequency. The advantages and limitations of the method are discussed.
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