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Determination of Orientation Averages for Partially Aligned low Symmetry Molecules

 

作者: Jacek Waluk,   ErikW. Thulstrup,  

 

期刊: Spectroscopy Letters  （Taylor Available online 1991）
卷期: Volume 24, issue 7-8  

页码: 951-957

 

ISSN:0038-7010

 

年代: 1991

 

DOI:10.1080/00387019108020674

 

出版商: Taylor & Francis Group

 

关键词: transition moment;polarization spectroscopy;linear dichroism;fluorescence polarization;benz[a]anthracene

 

数据来源: Taylor

 

摘要:

A graphical procedure is presented which allows a determination of the average alignment of the molecular axes in partially oriented, low-symmetry planar molecules from the results of linear dichroism and fluorescence polarization spectroscopy. When applied to benz[a]anthracene, the method makes it possible to extract information on the previously unknown origin of the second excited electronic state.

 

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