AbstractSome transition metal chelates of the Schiff's bases derived from salicylaldehyde ando‐anisidine,m‐anisidine andp‐anisidine have been isolated and characterized. The structures of these complexes have been discussed on the basis of their elemental analyses, conductivities, magnetic moment values, electronic and infrared spectral data.The Ni2+, Cu2+and Zn2+form ML2type compounds, UO22+and Fe3+form dimeric [UO2L2]and [Fe L2Cl]2respect