首页   按字顺浏览 期刊浏览 卷期浏览 Studies on the Transient Shear Flow Behavior of Liquid Crystalline Polymers
Studies on the Transient Shear Flow Behavior of Liquid Crystalline Polymers

 

作者: G. G. Viola,   D. G. Baird,  

 

期刊: Journal of Rheology  (AIP Available online 1986)
卷期: Volume 30, issue 3  

页码: 601-628

 

ISSN:0148-6055

 

年代: 1986

 

DOI:10.1122/1.549863

 

出版商: The Society of Rheology

 

数据来源: AIP

 

摘要:

An understanding of the flow behavior of liquid crystalline polymers (LCP's) is of immense practical value because of the potential to form high modulus materials from these polymers. These fluids exhibit a high degree of structure even in the quiescent state, as evidenced by their ability to transmit polarized light. In an effort to understand how the structure changes during flow, we have carried out a study on the transient shear flow properties of two thermotropic copolyesters of 60‐ and 80‐mole % para‐hydroxybenzoic acid (PHB) and polyethyleneterephthalate (PET) and a lyotropic system of poly‐p‐phenyleneterephthalamide (PPT) in 100% sulfuric acid. In one of the first theories concerned with the flow behavior of liquid crystalline fluids, which was proposed by Ericksen, the transient flow properties are all predicted to be due to changes in orientation of a director which describes the orientation of packets of rod‐like molecules. Stress growth, interrupted stress growth, and stress relaxation experiments are carried out on the three LCP's and at first sight are in qualitative agreement with the predictions of Ericksen's theory. However, wide angle X‐ray scattering analysis of quenched samples subjected to shear flow along with annealing experiments on oriented samples indicate that these materials do not orient readily in shear flow. Furthermore, orientation generated during extensional flow relaxes at a rate much faster than is indicated by the interrupted stress growth experiments. It is concluded that the stress growth response of LCP's is due to a disruption of a domain structure which exists within the fluid rather than to orientation changes of the domains of rod‐like molecules.

 

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