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MECHANISMS OF SYNFUEL DEGRADATION. 3. INTERACTIVE EFFECTS IN NITROGEN COMPOUND INDUCED STORAGE INSTABILITY IN SHALE DERIVED DIESEL FUEL

 

作者: JohnV. Cooney,   ErnaJ. Beal,   BruceD. Beaver,  

 

期刊: Fuel Science and Technology International  (Taylor Available online 1986)
卷期: Volume 4, issue 1  

页码: 1-18

 

ISSN:0884-3759

 

年代: 1986

 

DOI:10.1080/08843758608915789

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Deterioration in fuel quality upon storage has been a continuing problem in the utilization of middle distillate fuels. For diesel fuels. Instability is usually defined by the formation of insoluble sediments and gums and by the accumulation of hydroperoxides. Gravimetric accelerated storage stability tests conducted with model compounds as dopants in otherwise stable distillate fuels have demonstrated that oxidative condensation reactions of polar heterocylces are deleterious to stability. In particular, nitrogen containing aromatics (pyrroles, pyridinea, indoles, etc.) appear to be very harmful. Correlation of model dopant studies with results obtained with actual unstable fuels has indicated that autoxidation processes are usually not isolated reactions but are sensitive to the presence of other fuel constituents. In an effort to learn more about potential interactive effects, we have examined the autoxidation of two model compounds, 2, 5-dimethylpyrrole and 3-methylindole, in a shale diesel fuel in the presence of a second model dopant (a hydroperoxide, organic acid or base). The results presented support the notion that such interactive effects may be of critical importance in defining the stability of actual middle distillate fuels.

 

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