The Cr(III), Mn(II), Fe(II), Co(II), Ni(II), Cu(II), and Zn(II) polychelates of 4,4′-(4,4′-biphenylylenebisazo) salicylaldehyde-salicylic acid were prepared. The analytical data are found to be consistent with 1:1 (metal:ligand) stoichiometry. The polychelates were further characterized by conductivities, magnetic moment, as well as electronic and infrared spectral properties. All polychelates are found to have an octahedral stereochemistry.