Studies on the formation of complex compounds between Uranyl Nitrate and transitional metal Nitrate. The system: Th(No3)4UO2(No3)2H2O
作者:
S. S. Gupta,
S. D. Marwah,
期刊:
Journal für Praktische Chemie
(WILEY Available online 1966)
卷期:
Volume 31,
issue 1‐2
页码: 55-60
ISSN:0021-8383
年代: 1966
DOI:10.1002/prac.19660310108
出版商: WILEY‐VCH Verlag GmbH
数据来源: WILEY
摘要:
AbstractDetermination of conductance, pH, Spectrophotometry, and Refractive‐Index measurements of a series of mixed solutions of uranyl nitrate and thorium nitrate, indicate the existence of one definite complex‐compound in the solution namely\documentclass{article}\pagestyle{empty}\begin{document}$$ {\rm Th(NO}_{\rm 3} {\rm)}_{\rm 4} - {\rm UO}_{\rm 2} ({\rm NO}_{\rm 3})_2 $$\end{document}Monovariation method of NNYARand PANDE(1), has been followed in the preparation of the solution and in the investigation of properties. Aqueous solution of the uranyl nitrate and thorium nitrate were prepared in such a way that the concentration of uranyl nitrate was kept constant, while that of thorium nitrate was varied systematically, and the physico‐chemical properties recorded. When the values are plotted against the concentration of thorium nitrate curves are obtained with the specific breaks. The kink occurs at exact stoichiometric ratio of the concentrations corresponding to the compound noted
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