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Backbone effects on the anchoring of side-chain polymer liquid crystals

 

作者: B. JEROME,   J. COMMANDEUR,   W. H. DE JEU,  

 

期刊: Liquid Crystals  (Taylor Available online 1997)
卷期: Volume 22, issue 6  

页码: 685-692

 

ISSN:0267-8292

 

年代: 1997

 

DOI:10.1080/026782997208785

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

By comparing the anchoring behaviour of (end-on) side chain polymer liquid crystals with that of the corresponding low molecular mass liquid crystals, we have studied the effect of the backbone on the anchoring of side chain polymer liquid crystals. We can distinguish two different effects: the loss of rotational freedom of the side groups and the interaction of the polymer chain with the surface. In the case of free surfaces, we can formulate a general rule stating that compounds with side groups ending with an aliphatic chain (at least four carbon atoms long) exhibit a homeotropic anchoring, and compounds with side groups ending with a polar group exhibit a planar anchoring.

 

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