The kinetics of successive addition of oxirane to alkanethiols in the presence of basic catalysts
作者:
Jan Chlebicki,
Zbigniew Cichacz,
期刊:
International Journal of Chemical Kinetics
(WILEY Available online 1989)
卷期:
Volume 21,
issue 1
页码: 21-29
ISSN:0538-8066
年代: 1989
DOI:10.1002/kin.550210103
出版商: John Wiley&Sons, Inc.
数据来源: WILEY
摘要:
AbstractRate constants and activation parameters of direct reaction of oxirane with certain alkyl‐2‐hydroxyethyl sulfides and/or successive oxyethylene adducts in the presence of basic catalyst were studied at temperatures 323–353 K. The reactions were found to be of the first order with respect to oxirane, sulfide, and catalyst concentrations. The kinetics are consistent with a termolecular mech
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