Use of rheological measurements to estimate the molecular weight distribution of linear polyethylene
作者:
Paula M. Wood‐Adams,
John M. Dealy,
期刊:
Journal of Rheology
(AIP Available online 1996)
卷期:
Volume 40,
issue 5
页码: 761-778
ISSN:0148-6055
年代: 1996
DOI:10.1122/1.550763
出版商: The Society of Rheology
关键词: Molecular weight distribution, rheological estimate;Linear polyethylene, molecular weight distribution;POLYETHYLENES;MOLECULAR WEIGHT;VISCOSITY;RHEOLOGY
数据来源: AIP
摘要:
An important characteristic of a polymer is its molecular weight distribution (MWD). The MWD affects its processing characteristics and its solid state performance. The traditional analytical method for determining MWD is gel permeation chromatography (GPC). However, GPC results depend strongly on the skill and experience of the operator and are not sensitive to small amounts of high molecular weight material that can have an important effect on processing and product properties. It is known that rheological properties depend on MWD, and it has been proposed that viscosity or complex viscosity data can be used to infer the MWD for commercial polymers. Although there has been some controversy as to whether this is feasible, recent results of Shaw, Tuminello, and others indicate that for linear polymers this is, in theory, possible. However, limitations in the accessible frequency range, as well as inevitable experimental errors, pose serious barriers to the use of such a procedure. We have investigated the severity of these barriers and have shown that within certain limits, complex viscosity data can be used to infer a realistic MWD for linear polyethylenes.
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