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Direct and Second Order Analogue Derivative Extraction-Spectrophotometric Determination of Iron with 2 (4, 5-Dimethyl-2-Thiazolylazo)-4, 6-Dimethylphenol

 

作者: M.J. Sánchez,   B. Santana,   J.L. Peña,   F.J. García Montelongo,  

 

期刊: Analytical Letters  (Taylor Available online 1988)
卷期: Volume 21, issue 12  

页码: 2345-2357

 

ISSN:0003-2719

 

年代: 1988

 

DOI:10.1080/00032718808059914

 

出版商: Taylor & Francis Group

 

关键词: 2-(4, 5-dimethyl-2-thiazolylazo)-4, 6-dime-thylphenol;iron;extraction-spectrophoto-metry;water

 

数据来源: Taylor

 

摘要:

An extraction-spectrophotometric method for the determination of trace amounts of iron based on its extraction into chloroform with 2-(4, 5-dimethyl-2-thiazolylazo)-4, 6-dimethylphenol has been developed, which allows the determination of 5–28 μg Fe (ϵ773= 1.38×1041. mol−1. cm−1). The use of second order analogue derivative spectrophotometry allows the determination of down to 0.2–5 μg, Fe. The methods are quite selective and have been applied to the determination of iron in mineral waters.

 

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