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Conformal Domain Miniaturization and Adaptive Monoclinic (Pseudo‐orthorhombic) Ferroelectric States

 

作者: Y. M. Jin,   Yu Wang,   A. G. Khachaturyan,   J. F. Li,   D. Viehland,  

 

期刊: AIP Conference Proceedings  (AIP Available online 1903)
卷期: Volume 677, issue 1  

页码: 84-97

 

ISSN:0094-243X

 

年代: 1903

 

DOI:10.1063/1.1609941

 

出版商: AIP

 

数据来源: AIP

 

摘要:

Ferroelectric and ferroelastic phases with very low domain wall energies have been shown to form miniaturized microdomain structures. A theory of an adaptive ferroelectric phase has been developed to predict the microdomain‐averaged crystal lattice parameters of this structurally inhomogeneous state. The theory is an extension of conventional martensite theory, applied to ferroelectric systems with very low domain wall energies. The cases of ferroelectric microdomains of tetragonal (FEt) symmetry are considered. It is shown that a nano‐scale coherent mixture of microdomains can be interpreted as an adaptive ferroelectric phase, whose microdomain‐averaged crystal lattice is monoclinic. The crystal lattice parameters of this monoclinic phase are self‐adjusting parameters, which minimize the transformation stress. Self‐adjustment is achieved by application of the invariant plane strain (IPS) to the parent cubic lattice, and the value of the self‐adjusted parameters constitutes a mixture of the lattice constants of the parent and product phases. Experimental investigations of Pb(Mg1/3Nb2/3)O3‐PbTiO3(PMN‐PT) and Pb(Zn1/3Nb2/3)O3‐PbTiO3(PZN‐PT) single crystals confirm many of the predictions of this theory. © 2003 American Institute of Physics

 

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