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The second virial coefficient of planar dumb-bells

 

作者: J.S. Rowlinson,   J. Talbot,   D.J. Tildesley,  

 

期刊: Molecular Physics  (Taylor Available online 1985)
卷期: Volume 54, issue 5  

页码: 1065-1071

 

ISSN:0026-8976

 

年代: 1985

 

DOI:10.1080/00268978500100851

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

A fluid whose molecules are pairs of hard discs can serve as a reference system for the study of adsorbed diatomic molecules. We obtain its second virial coefficient, point out an ambiguity in the definition of this coefficient when the separation of the centres of the disc exceeds √2 times their diameter, and compare the results with those for a capped rectangle, which is the equivalent hard convex body.

 

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